ࡱ>  ~ bjbj΀ 48((kkkkk$MWWWWW222$ZUk22222kkWW8882/kWkW82888WpǀPM:<8x0M8F8k8@228222228222M2222222222222( 1: L-ALANYL-L-ALANYL-L-ALANINE METHYL ESTER ACETATE CAS # 41036275 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at -20C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Store at -20%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACCASE CAS # 80498153 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May cause irritation. May be harmful by inhalation, ingestion, or skin absorption. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20C REACTIVE PROPERTIES STORAGE Store at -20%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACMOID CAS # 33869215 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 S PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACTALBUMIN CAS # 68458877 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure.STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACTALBUMIN ENZYMATIC HYDROLYSATE CAS # 9073603 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACTAMIDE CAS # 89673712 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACTATE DEHYDROGENASE (L-) CAS # 9001609 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. Store at 2-8C Keep tightly closed. Do not freeze. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8C SPECIAL REQUIREMENTS Do not freeze. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACTIC ACID CAS # 50215 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3543.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Bases, Oxidizing agents, Reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 38 41 Risk Statements: Irritating to skin. Risk of serious damage to eyes. S: 26 39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 40 mg/m3 DOE Ceiling Limit 300 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACTIC ACID (D-) CAS # 10326417 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3730.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 38 41 Risk Statements: Irritating to skin. Risk of serious damage to eyes. S: 26 39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACTIC ACID (DL-) CAS # 598823 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3543.0 mg/Kg INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. WATER SPRAY. TOXIC EMISSIONS WHEN BURNED: N MONOXIDE REACTIVE PROPERTIES MINOR AMOUNTS OF ACID CAUSE ACROLEIN TO POYLMERIZE WITH RELEASE OF HEAT.BENZYL ALCOHOL CONTAINING ACIDIC CONSTITUENTS AND DISSOLVED IRON WAS FOUND TOPOLYMERIZE WITH A RAPID TEMPERATURE INCREASE WHEN HEATED IN EXCESS OF100C.(AMINES, PYRIDINE, AND ALKALI HYDROXIDES ACT AS INHIBITORS AND PREVENTPOLYMERIZATION.) REACT VIGOROUSLY WITH LITHIUM ALUMINUM HYDRIDE. HIGHCONCENTRATIONS OF ACID REACT EXPLOSIVELY WITH NICKEL NITRIDE AND HEAT.INITIATE A FAST DECOMPOSITION OF SODIUM OZONATE. REACTS WITH THORIUMPHOSPHIDE TO RELEASE SPONTANEOUSLY FLAMMABLE PHSOPHINE. REACTS VIOLENTLY WITHTRI-ISO-BUTYL ALUMINUM. A MIXTURE OF 5 PARTS LACTIC ACID, 5 PARTS NITRICACID, 2 PARTS WATER, AND 1 PART HYDROFLUORIC ACID BEING STORED IN A PLASTICBOTTLE RUPTURED WITH EXPLOSIVE FORCE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACTIC ACID (DL-) CAS # 79334 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3543.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Will not occur SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 230 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep tightly closed. Hygroscopic. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8%C SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 38 41 Risk Statements: Irritating to skin. Risk of serious damage to eyes. S: 26 39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACTIC ACID HEMICALCIUM HYDRATE (L-) CAS # 41372229 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: ZATION WILL NOT OCCUR The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACTIC ACID SODIUM (DL-) CAS # 312856 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. TOXIC EMISSIONS WHEN BURNED: WILL NOT OCCUR US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACTOPHENOL BLUE CAS # 55068661 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . G . I . . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Readily absorbed through skin. Toxic if absorbed through skin. Eye Contact: Causes burns. Inhalation: Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Kidneys. Liver. Pancreas. Spleen. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Ingestion can cause circulatory collapse, tachypnea, paralysis, convulsions, coma, necrosis of mouth and G.I. tract, jaundice, death from respiratory failure, sometimes from cardiac arrest. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25-48/20/21/22-34-68 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Harmful: danger of serious damage to health by prolonged exposure through inhalation in contact with skin, and if swallowed. Causes burns. Possible risk of irreversible effects. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACTOSE (BETA-) CAS # 5965662 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LACTOSE MONOHYDRATE (ALPHA,D-) CAS # 5989811 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 10000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LAEMMLI BUFFER A CAS # 52 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: ON MONOXIDENITROGEN OXIDES The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LAEMMLI BUFFER B CAS # 53 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: ON MONOXIDENITROGEN OXIDES The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LAMINARIN CAS # 9008224 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LAMINARINASE CAS # 62213143 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fire conditions. Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LANOLIN CAS # 8006540 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Aspiration or inhalation may cause chemical pneumonitis. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION US CLASSIFICATION AND LABEL TEXT The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LANSOPRAZOLE CAS # 103577453 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Causes eye and skin irritation. May be harmful by inhalation, ingestion, or skin absorption. TARGET ORGAN(S) OR SYSTEM(S) G.I. System. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Sulfur oxides Nitrogen oxides Store at 2-8C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LANTHANUM CAS # 7439910 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 W INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Sulfur, Phosphorus, Halogens, Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Dry chemical powder. Do not use water. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. STORAGE: Keep tightly closed. Handle and store under argon\. SPECIAL REQUIREMENTS Air and moisture sensitive. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LANTHANUM CHLORIDE CAS # 10025840 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4184.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Severe skin irritant. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Severe eye irritant. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LANTHANUM CHLORIDE CAS # 20211761 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4184.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Severe skin irritant. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Severe eye irritant. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LANTHANUM CHLORIDE ANHYDROUS CAS # 10099588 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4184.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure.STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 6 mg/m3 DOE Short Term Exposure Limit 20 mg/m3 DOE Ceiling Limit 125 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LANTHANUM HEXABORIDE CAS # 12008218 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 14.7 mg/m3 DOE Short Term Exposure Limit 44 mg/m3 DOE Ceiling Limit 75 mg/m3 Immediately Dangerous to Life and Health 350 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LANTHANUM NITRATE HYDRATE CAS # 10277437 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 OX INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Repeated exposure can cause: Blood effects. Chemical pneumonitis. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xi Indication of Danger: Oxidizing. Irritant. R: 8 36/37/38 Risk Statements: Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. S: 17 26 36 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 mg/m3 DOE Short Term Exposure Limit 5 mg/m3 DOE Ceiling Limit 35 mg/m3 Immediately Dangerous to Life and Health 150 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LANTHANUM TRIFLUOROMETHANESULFONATE CAS # 52093262 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Hydrogen fluoride REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LANTHANUM(III) OXIDE CAS # 1312818 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 9968.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents Carbon dioxide. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Incompatible Materials: Absorbs carbon dioxide from air\. SPECIAL REQUIREMENTS Store under inert gas. Air sensitive. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 40 mg/m3 DOE Short Term Exposure Limit 125 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LATEX CAS # 000016 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LATEX CAS # 16 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LAUDANOSOLINE HYDROBROMIDE TRIHYDRATE CAS # 303136745 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. S: 27 28 36/37/39 45 Safety Statements: Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LAURIC ACID CAS # 143077 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 OX ACUTE TOXICTY RISK INDEX 1.6 - LD50 12000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .002334 mm Hg @ 20 C Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Bases, Oxidizing agents, Reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LAURIC ACID METHYL ESTER CAS # 111820 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .005500 mm Hg @ 20 C FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LAURIC ACID SODIUM CAS # 629254 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. IRRITATION DATA skin Rat 28 mg 24H Remarks: Severe irritation effect PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES STORAG GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LAURIC ANHYDRIDE CAS # 645669 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LAUROYL CHLORIDE CAS # 112163 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 1 W INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 284 F Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Amines, Do not allow contact with water. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 37 Risk Statements: Causes burns. Irritating to respiratory system. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LAUROYLSARCOSINE CAS # 97789 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LAURYL SARCOSINE SODIUM (N-) CAS # 137166 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause coughing, wheezing, respiratory distress, and diarrhea. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD CAS # 7439921 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX A B . . . . . . I J . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 5.3 NEUROTOXIC - RISK INDEX 4.0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Blood. Kidneys. Female reproductive system. Male reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE Anemia. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids. FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. Noncombustible. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 61 33 40 48/20 62 Risk Statements: May cause harm to the unborn child. Danger of cumulative effects. Limited evidence of a carcinogenic effect. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Possible risk of impaired fertility. S: 53 36/37 45 Safety Statements: Avoid exposure - obtain special instructions before use. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .05 mg/m3 DOE Short Term Exposure Limit .15 mg/m3 DOE Ceiling Limit .25 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD CARBONATE CAS # 598630 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. May cause irritation. TARGET ORGAN(S) OR SYSTEM(S) Blood. Kidneys. Female reproductive system. Male reproductive system. Nerves. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Lead/lead oxides REACTIVE PROPERTIES User Exposure: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T-N Indication of Danger: Toxic. Dangerous for the environment. R: 61-20/22-33-62-50/53 Risk Statements: May cause harm to the unborn child. Harmful by inhalation and if swallowed. Danger of cumulative effects. Possible risk of impaired fertility. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53-45-60-61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 100 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0645 mg/m3 DOE Short Term Exposure Limit .193 mg/m3 DOE Ceiling Limit 4 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD CHROMATE CAS # 7758976 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . K . NFPA HAZARD CODES (H,F,R,O) 0 0 1 OX NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Male reproductive system. Lungs. Blood. Kidneys. Nerves. Female reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Finely powdered metals, Organic materials. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Unsuitable: Do not store near, nor allow contact with, clothing and other combustible material. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T-N Indication of Danger: Toxic. Dangerous for the environment. R: 61-33-40-50/53-62 Risk Statements: May cause harm to the unborn child. Danger of cumulative effects. Limited evidence of a carcinogenic effect. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risk of impaired fertility. S: 53-45-60-61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 15 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0311 mg/m3 DOE Short Term Exposure Limit .186 mg/m3 DOE Ceiling Limit 1 mg/m3 Immediately Dangerous to Life and Health 93.2 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD MONOXIDE CAS # 1317368 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . I . K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Reproductive system. G.I. System. Nerves. Blood. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Weakness. Headache. Nausea. Exposure can cause: Lead compounds can cause anorexia, vomiting, malaise, convulsions, and may leave permanent brain damage. Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, possible paralysis, PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 10.0 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Strong oxidizing agents, Hydrogen peroxide. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T-N Indication of Danger: Toxic. Dangerous for the environment. R: 61-20/22-33-62-50/53 Risk Statements: May cause harm to the unborn child. Harmful by inhalation and if swallowed. Danger of cumulative effects. Possible risk of impaired fertility. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53-45-60-61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 100 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0539 mg/m3 DOE Short Term Exposure Limit .0539 mg/m3 DOE Ceiling Limit .0539 mg/m3 Immediately Dangerous to Life and Health 108 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD NITRATE CAS # 10099748 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . K . NFPA HAZARD CODES (H,F,R,O) 2 0 1 OX NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Female reproductive system. Male reproductive system. Blood. Kidneys. Nerves. SIGNS AND SYMPTOMS OF EXPOSURE Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Organic materials, Finely powdered metals. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Lead/lea oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: O-T-N Indication of Danger: Oxidizing. Toxic. Dangerous for the environment. R: 61-8-20/22-33-62-50/53 Risk Statements: May cause harm to the unborn child. Contact with combustible material may cause fire. Also harmful by inhalation and if swallowed. Danger of cumulative effects. Possible risk of impaired fertility. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53-45-60-61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 100 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0799 mg/m3 DOE Short Term Exposure Limit .6 mg/m3 DOE Ceiling Limit 4 mg/m3 Immediately Dangerous to Life and Health 160 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD OXIDE, RED CAS # 1314416 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . F G . . . K . NFPA HAZARD CODES (H,F,R,O) 2 0 1 OX INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Kidneys. Nerves. Female reproductive system. Male reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 10.0 mm Hg @ 20 C Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Lead/lead oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATIO Symbol of Danger: O-T-N Indication of Danger: Oxidizing. Toxic. Dangerous for the environment. R: 61-8-20/22-33-62-50/53 Risk Statements: May cause harm to the unborn child. Contact with combustible material may cause fire. Also harmful by inhalation and if swallowed. Danger of cumulative effects. Possible risk of impaired fertility. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53-45-60-61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 100 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0551 mg/m3 DOE Short Term Exposure Limit .165 mg/m3 DOE Ceiling Limit .276 mg/m3 Immediately Dangerous to Life and Health 110 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD SUBACETATE CAS # 1335326 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C . . . . . I . K . NFPA HAZARD CODES (H,F,R,O) 1 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Brain. Central nervous system. Peripheral nervous system. G.I. System. Skeletal muscle. Kidneys. Female reproductive system. Male reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Lead/lead oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 61 33 40 48/22 50/53 Risk Statements: May cause harm to the unborn child. Danger of cumulative effects. Limited evidence of a carcinogenic effect. Also harmful: danger of serious damage to health by prolonged exposure if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53 60 45 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. This material and its container must be disposed of as hazardous waste. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 100 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .065 mg/m3 DOE Short Term Exposure Limit .195 mg/m3 DOE Ceiling Limit 130 mg/m3 Immediately Dangerous to Life and Health 130 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD TETRAACETATE CAS # 546678 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . K . NFPA HAZARD CODES (H,F,R,O) 1 0 1 OX NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Peripheral nervous system. Central nervous system. Female reproductive system. Male reproductive system. Blood. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Alcohols, Strong acids, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Lead/lead oxides Store at 2-8C Store under inert gas. Keep tightly closed. Do not store near, nor allow contact with, clothing and Store under inert gas. Air and moisture sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Store under inert gas. Keep tightly closed. Unsuitable: Do not store near, nor allow contact with, clothing and other combustible material. Store at 2-8%C SPECIAL REQUIREMENTS Store under inert gas. Air and moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O T N Indication of Danger: Oxidizing. Toxic. Dangerous for the environment. R: 61 8 20/22 33 50/53 62 Risk Statements: May cause harm to the unborn child. Contact with combustible material may cause fire. Harmful by inhalation and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risk of impaired fertility. S: 53 17 36/37 45 60 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. Keep away from combustible material. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD(II) ACETATE CAS # 301042 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX A B C . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3 - TD50 46.6 mg/Kg HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 5.3 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.5 - LD50 16.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: FUMES OF: REACTIVE PROPERTIES REACTION WITH POTASSIUM BROMATE TO FORM LEAD BROMATE CAUSED AN EXPLOSIONWHICH KILLED TWO PEOPLE. Immediately Dangerous to Life and Health 100 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0785 mg/m3 DOE Short Term Exposure Limit .235 mg/m3 DOE Ceiling Limit 75 mg/m3 Immediately Dangerous to Life and Health 157 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD(II) ACETATE TRIHYDRATE CAS # 6080564 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C . E . . . I J K . NFPA HAZARD CODES (H,F,R,O) 4 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.5 - LD50 16.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Central nervous system. Peripheral nervous system. G.I. System. Skeletal muscle. Kidneys. Female reproductive system. Male reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Lead/lead oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE Incompatible Materials: Absorbs carbon dioxide from air\. SPECIAL REQUIREMENTS Light sensitive. Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 61 33 48/22 50/53 62 Risk Statements: May cause harm to the unborn child. Danger of cumulative effects. Also harmful: danger of serious damage to health by prolonged exposure if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risk of impaired fertility. S: 53 45 60 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 100 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0915 mg/m3 DOE Short Term Exposure Limit .275 mg/m3 DOE Ceiling Limit 100 mg/m3 Immediately Dangerous to Life and Health 183 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD(II) CHLORIDE CAS # 7758954 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . K . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1500.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Kidneys. Nerves. Female reproductive system. Male reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .0400 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Lead/lead oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 61 20/22 33 50/53 62 Risk Statements: May cause harm to the unborn child. Harmful by inhalation and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risk of impaired fertility. S: 53 45 60 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 100 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0671 mg/m3 DOE Short Term Exposure Limit .201 mg/m3 DOE Ceiling Limit 7.5 mg/m3 Immediately Dangerous to Life and Health 134 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD(II) PERCHLORATE CAS # 13637768 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . I . K . NFPA HAZARD CODES (H,F,R,O) 0 0 1 OX SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. May be fatal if inhaled, swallowed, or absorbed through skin. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Blood. Kidneys. Male reproductive system. Female reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, possible paralysis, and encephalopathy can result. Additional symptoms of overexposure include: joint and muscle pain, weakness of the extensor muscles (frequently the hand and wrist), headache, dizziness, abdominal pain, diarrhea, constipation, nausea, vomiting, blue line on the gums, insomnia, and metallic taste. High body levels produce increased cerebrospinal pressure, brain damage, and stupor leading to coma and often death. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Organic materials, Finely powdered metals, Strong reducing agents. FIRE EXTINGUISHER: Water spray. TOXIC EMISSIONS WHEN BURNED: Lead/lead oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Unsuitable: Do not store near, nor allow contact with, clothing and other combustible material. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O T N Indication of Danger: Oxidizing. Toxic. Dangerous for the environment. R: 61 8 20/22 33 50/53 62 Risk Statements: May cause harm to the unborn child. Contact with combustible material may cause fire. Also harmful by inhalation and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risk of impaired fertility. S: 53 45 60 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD(II) SULFATE CAS # 7446142 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Blood. Kidneys. Nerves. Female reproductive system. Male reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, possible paralysis, and encephalopathy can result. Additional symptoms of overexposure include: joint and muscle pain, weakness of the extensor muscles (frequently the hand and wrist), headache, dizziness, abdominal pain, diarrhea, constipation, nausea, vomiting, blue line on the gums, insomnia, and metallic taste. High body levels produce increased cerebrospinal pressure, brain damage, and stupor leading to coma and often death. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Potassium, Strong bases. FIRE EXTINGUISHER: Dry chemical powder. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Lead/lead oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 61 20/22 33 50/53 62 Risk Statements: May cause harm to the unborn child. Harmful by inhalation and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risk of impaired fertility. S: 53 45 60 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 100 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0732 mg/m3 DOE Short Term Exposure Limit .2196 mg/m3 DOE Ceiling Limit 30 mg/m3 Immediately Dangerous to Life and Health 146 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD(II) SULFIDE CAS # 1314870 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . F G . I . K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Kidneys. Nerves. Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents, Iodine compounds, Hydrogen peroxide. FIRE EXTINGUISHER: Dry chemical powder. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Lead/lead oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 61 20/22 33 50/53 62 Risk Statements: May cause harm to the unborn child. Harmful by inhalation and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risk of impaired fertility. S: 53 45 60 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 100 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0577 mg/m3 DOE Short Term Exposure Limit .173 mg/m3 DOE Ceiling Limit 350 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD(II) TETRAFLUOROBORATE CAS # 13814965 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. TARGET ORGAN(S) OR SYSTEM(S) Blood. Kidneys. Nerves. SIGNS AND SYMPTOMS OF EXPOSURE Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Boron trifluoride Lead/lead oxides REACTIVE PROPERTIES User Exposure: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 61 20/22 33 50/53 62 Risk Statements: May cause harm to the unborn child. Harmful by inhalation and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risk of impaired fertility. S: 53 45 60 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 250 mg/m US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0919 mg/m3 DOE Short Term Exposure Limit .276 mg/m3 DOE Ceiling Limit .459 mg/m3 Immediately Dangerous to Life and Health 184 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEAD(IV) OXIDE CAS # 1309600 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . K . NFPA HAZARD CODES (H,F,R,O) 1 1 1 OX NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Blood. Kidneys. Male reproductive system. Female reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Lead compounds can cause anorexia, vomiting, malaise, convulsions, and may leave permanent brain damage. Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, possible PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Finely powdered metals, Strong reducing agents. FIRE EXTINGUISHER: Water spray. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: O-T-N Indication of Danger: Oxidizing. Toxic. Dangerous for the environment. R: 61-8-20/22-33-62-50/53 Risk Statements: May cause harm to the unborn child. Contact with combustible material may cause fire. Also harmful by inhalation and if swallowed. Danger of cumulative effects. Possible risk of impaired fertility. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53-45-60-61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 100 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0577 mg/m3 DOE Short Term Exposure Limit .1731 mg/m3 DOE Ceiling Limit 20 mg/m3 Immediately Dangerous to Life and Health 115 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LECTIN CAS # 63231572 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 42/43 Risk Statements: May cause sensitization by inhalation and skin contact. S: 36 Safety Statements: Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LECTIN ABRIN A CAS # 53597232 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C D E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 5++ - LD50 .0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. TOXIC EMISSIONS WHEN BURNED: WILL NOT OCCUR The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEPIDINE CAS # 491350 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .002100 mm Hg @ 20 C FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEUCINE (D-) CAS # 328381 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEUCINE (DL-) CAS # 328392 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. The levorotary (l) forms of leucine, isoleucine, and valine have been found to have tumor-promoting activity for bladder carcinomas. Science 231, 843, 21 February 1986.ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. The levorotary (l) forms of leucine, isoleucine, and valine have been found to have tumor-promoting activity for bladder carcinomas. Science 231, 843, 21 February 1986.ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. The levorotary (l) forms of leucine, isoleucine, and valine have been found to have tumor-promoting activity for bladder carcinomas. Science 231, 843, 21 February 1986.ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. The levorotary (l) forms of leucine, isoleucine, and valine have been found to have tumor-promoting activity for bladder carcinomas. Science 231, 843, 21 February 1986.ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. The levorotary (l) forms of leucine, isoleucine, and valine have been found to have tumor-promoting activity for bladder carcinomas. Science 231, 843, 21 February 1986.ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. The levorotary (l) forms of leucine, isoleucine, and valine have been found to have tumor-promoting activity for bladder carcinomas. Science 231, 843, 21 February 1986.ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. The levorotary (l) forms of leucine, isoleucine, and valine have been found to have tumor-promoting activity for bladder carcinomas. Science 231, 843, 21 February 1986.ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. The levorotary (l) forms of leucine, isoleucine, and valine have been found to have tumor-promoting activity for bladder carcinomas. Science 231, 843, 21 February 1986.ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. The levorotary (l) forms of leucine, isoleucine, and valine have been found to have tumor-promoting activity for bladder carcinomas. Science 231, 843, 21 February 1986. carcinomas. Science 231, 843, 21 February 1986. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEUCINE (FMOC,L-) CAS # 35661600 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEUCINE (L-) CAS # 61905 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The levorotary (l) forms of leucine, isoleucine, and valine have been found to have tumor-promoting activity for bladder carcinomas. Science 231, 843, 21 February 1986. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEUCINE AMINOPEPTIDASE CAS # 9001610 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep container closed. Store away from heat. REACTIVE PROPERTIES STORAGE: Keep container closed. Store away from heat. Store at 2-8%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEUCINE AMINOPEPTIDASE CAS # 9054631 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep container closed. Store away from heat. REACTIVE PROPERTIES STORAGE: Keep container closed. Store away from heat. Store at 2-8%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEUCINE CHLOROMETHYL KETONE HYDROCHLORIDE (L-) CAS # 54518922 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 S PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: REACTIVE PROPERTIES STORAGE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEUCINE ENKEPHALIN SYNTHETIC ACETATE CAS # 81678162 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE Although the physiological role of the enkephalins has not been completely elucidated, they are known to block inhibitory pathways in the vertebrate CNS and their possible effects on pain perception, addictive states, and psychiatric disorders have been investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at -20C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEUCINE METHYL ESTER HYDROCHLORIDE (L-) CAS # 7517193 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEUCINE NAPHTHYLAMIDE HYDROCHLORIDE (L,BETA-) CAS # 893367 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE These chronic effects are suggested from analogy to beta-naphthylamine, RTECS# QM2100000. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEUCINOL (L-) CAS # 7533406 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. - PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 195 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame\. SPECIAL REQUIREMENTS Store under inert gas.- GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEUPEPTIN CAS # 103476897 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 3 0 1 ACUTE TOXICTY RISK INDEX 2.8 - LD50 720.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. CONDITIONS AGGRAVATED BY EXPOSURE A protease inhibitor. The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong bases. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Store at -20C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEVAMISOLE HYDROCHLORIDE CAS # 16595805 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 180.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Immune system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 36/37/39 45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LEVULINIC ACID CAS # 123762 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1850.0 mg/Kg INHALATION RISK INDEX 1.1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .200 mm Hg @ 20 C FLASH POINT 208.4 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Bases, Oxidizing agents, Reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LIGHT GREEN SF YELLOWISH CAS # 5141208 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes irritation. TARGET ORGAN(S) OR SYSTEM(S) Male reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Water spray. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LIMONENE (D-) CAS # 5989275 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 2 0 ACUTE TOXICTY RISK INDEX 2 - LD50 4400.0 mg/Kg INHALATION RISK INDEX 1.8 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea, vomiting, diarrhea. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 4.2 mm Hg @ 20 C FLASH POINT 118 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi-N Indication of Danger: Irritant. Dangerous for the environment. R: 10-38-43-50/53 Risk Statements: Flammable. Irritating to skin. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 24-37-60-61 Safety Statements: Avoid contact with skin. Wear suitable gloves. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 30 ppm DOE Short Term Exposure Limit 90 ppm DOE Ceiling Limit 150 ppm Immediately Dangerous to Life and Health 350 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LIMONENE (DL-) CAS # 138863 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5300.0 mg/Kg INHALATION RISK INDEX 1.3 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE mm Hg @ 20 C FLASH POINT 110 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi-N Indication of Danger: Irritant. Dangerous for the environment. R: 10-38-43-50/53 Risk Statements: Flammable. Irritating to skin. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 24-37-60-61 Safety Statements: Avoid contact with skin. Wear suitable gloves. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LIMONENE (L-) CAS # 5989548 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 2 0 INHALATION RISK INDEX 1.7 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 3.0 mm Hg @ 20 C FLASH POINT 109.4 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi N Indication of Danger: Irritant. Dangerous for the environment. R: 10 38 43 50/53 Risk Statements: Flammable. Irritating to skin. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 24 37 60 61 Safety Statements: Avoid contact with skin. Wear suitable gloves. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LINOLEIC ACID CAS # 60333 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 ACUTE TOXICTY RISK INDEX .5 - LD50*** mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Bases, Oxidizing agents, Reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20C Keep tightly closed. Store under nitrogen. Store under inert gas. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen. Store at -20%C SPECIAL REQUIREMENTS Store under inert gas. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LINOLENIC ACID CAS # 463401 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Bases, Oxidizing agents, Reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20C Air and light sensitive. Store under inert gas. Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20%C SPECIAL REQUIREMENTS Air and light sensitive. Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION US CLASSIFICATION AND LABEL TEXT Indication of Danger: Irritant. Risk Statements: Irritating to eyes, respiratory system and skin. Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LINOLENIC ACID (GAMMA-) CAS # 506263 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. May be harmful by inhalation, ingestion, or skin absorption. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 230 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20C REACTIVE PROPERTIES STORAGE Store at -20%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LINSEED OIL CAS # 8001261 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure can cause: Dermatitis. IRRITATION DATA skin Human 300 mg 3D I Remarks: Moderate irritation effect PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Forms explosive mixtures with:, Chlorine, Zinc, Oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Use water spray to cool fire-exposed containers. TOXIC EMISSIONS WHEN BURNED: Lead/lead oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 43 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 10 mg/m3 Immediately Dangerous to Life and Health 60 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LIPASE CAS # 9001621 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. Store at -20C Keep tightly closed. Store away from heat. Moisture sensitive. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store away from heat\. Store at -20C SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LIPOAMIDE CAS # 3206733 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin andclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LIPOPHILIC SEPHADEX CAS # 9041376 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure.STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 Safety Statements: Do not breathe dust. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LIPOPOLYSACCHARIDE CAS # 46 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LISINOPRIL CAS # 76547983 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 8500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Cardiovascular system. Bone marrow. SIGNS AND SYMPTOMS OF EXPOSURE Causes a fall in blood pressure. Exposure can cause: Dizziness. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM CAS # 7439932 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . B . . . . G . I . . . NFPA HAZARD CODES (H,F,R,O) 3 2 1 W HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable VAPOR PRESSURE .0300 mm Hg @ 20 C Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Iron and iron salts., Forms explosive mixtures with:, Phosphorus, Heavy metals, Sulfur, Oxygen, Nickel Avoid contact with acid. FIRE EXTINGUISHER: Use approved class D extinguishers or smother with drysand, dry ground limestone, or dry clay. Do not use water. Do not use carbon dioxide extinguisher on this material. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Store under argon\. Incompatible Materials: Do not allow contact with water GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 14/15 34 Risk Statements: Reacts violently with water, liberating extremely flammable gases. Causes burns. S: 8 43 45 Safety Statements: Keep container dry. In case of fire, use special powder for metal fire. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 400 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM ACETATE DIHYDRATE CAS # 6108174 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. SIGNS AND SYMPTOMS OF EXPOSURE Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Lithium oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 24/25 22 Safety Statements: Avoid contact with skin and eyes. Do not breathe dust. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 12.5 mg/m3 DOE Short Term Exposure Limit 35 mg/m3 DOE Ceiling Limit 250 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM ALUMINUM HYDRIDE CAS # 16853853 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 3 2 1 W,OX ACUTE TOXICTY RISK INDEX 5 - LD50 274.2 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 70.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Liver. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable Reacts violently with water Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive e - Oxidizer/Organic Peroxide l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Alcohols Reacts violently with water., Carboxylic acids, Peroxides, Chlorinated solvents, Halogens FIRE EXTINGUISHER: Use approved class D extinguishers or smother with drysand, dry ground limestone, or dry clay Do not use water. Do not use carbon dioxide extinguisher on this material. Do not use halocarbon extinguishers. TOXIC EMISSIONS WHEN BURNED: Aluminum oxide Lithium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Handle and store under argon\. Incompatible Materials: Do not allow contact with water Special REQUIREMENTS Handle and store under inert gas. Reacts violently with water. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 15 Risk Statements: Contact with water liberates extremely flammable gases. S: 7/8 24/25 43 Safety Statements: Keep container tightly closed and dry. Avoid contact with skin and eyes. In case of fire, use special powder for metal fire. Never use water. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 2 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2.81 mg/m3 DOE Short Term Exposure Limit 2.81 mg/m3 DOE Ceiling Limit 7.5 mg/m3 Immediately Dangerous to Life and Health 35 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM BISTRIMETHYLSILYLAMIDE CAS # 4039321 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . I . . . NFPA HAZARD CODES (H,F,R,O) 3 3 1 W SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Acids, Alcohols, Do not allow contact with water. FIRE EXTINGUISHER: Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Silicon oxide Lithium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid prolonged or repeated exposure. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water SPECIAL REQUIREMENTS Air sensitive. Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 14 34 Risk Statements: Highly flammable. Reacts violently with water. Causes burns. S: 16 26 36/37/39 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM BOROHYDRIDE CAS # 16949158 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . G . I J K . NFPA HAZARD CODES (H,F,R,O) 3 2 1 W ACUTE TOXICTY RISK INDEX 5 - LD50 283.2 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 80.0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Toxic if inhaled. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Nerves. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Exposure can cause: Gastrointestinal disturbances. Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Acid anhydrides, Amines, Ammonia, Chloroformates, Halogens, Phosphorus halides, Strong acids, Strong bases, Strong oxidizing agents. FIRE EXTINGUISHER: Use approved class D extinguishers or smother with drysand, dry ground limestone, or dry clay. Do not use water. Do not use dry chemical powder extinguisher on this material. TOXIC EMISSIONS WHEN BURNED: Liberates flammable/explosive hydrogen gas Borane/boron oxides REACTIVE PROPERTIES HANDLING: Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place\. Incompatible Materials: Avoid contact with acid. Do not allow contact with water Special REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F T Indication of Danger: Highly Flammable. Toxic. R: 14/15 23/24/25 34 Risk Statements: Reacts violently with water, liberating extremely flammable gases. Toxic by inhalation, in contact with skin and if swallowed. Causes burns. S: 26 36/37/39 43 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of fire, use dry powder. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4.03 mg/m3 DOE Short Term Exposure Limit 12.1 mg/m3 DOE Ceiling Limit 20.2 mg/m3 Immediately Dangerous to Life and Health 35 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM BROMIDE CAS # 7550358 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1800.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX 1.7 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S Central nervous system. Blood. SIGNS AND SYMPTOMS OF EXPOSURE Large doses of lithium compounds have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Anhydrous lithium bromide is extremely hygroscopic and contact with tissue can produce a dehydrating action resulting in localized burns. Inorganic bromides can cause rashes, especially of the face, resembling acne when inhalation or ingestion is prolonged. Overexposure can produce depression, emaciation with severe cases resulting in psychosis, and mental deterioration. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen bromide gas Lithium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1 mg/m3 DOE Short Term Exposure Limit 7 mg/m3 DOE Ceiling Limit 15 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM BUTOXIDE (TERT-) CAS # 1907331 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 W ACUTE TOXICTY RISK INDEX 2 - LD50 5425.8 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes burns. SIGNS AND SYMPTOMS OF EXPOSURE Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Acids, Reducing agents, Oxygen, Water, Alcohols, Chlorinated solvents, Halogens. FIRE EXTINGUISHER: Dry chemical powder. Do not use water. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. Store in a cool dry place. Handle and store under nitrogen\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 14 34 Risk Statements: Highly flammable. Reacts violently with water. Causes burns. S: 7/8 26 33 36/37/39 43 45 Safety Statements: Keep container tightly closed and dry. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take precautionary measures against static discharges. Wear suitable protective clothing, gloves, and eye/face protection. In case of fire, use dry powder. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM CARBONATE CAS # 554132 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 525.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 2170.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S Central nervous system. Kidneys. Cardiovascular system. Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea, vomiting, diarrhea. Anorexia. Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. Cyanosis and t-wave inversion have occurred in the breast-fed infants of women receiving lithium carbonate therapy. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .0200 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Lithium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36 Risk Statements: Harmful if swallowed. Irritating to eyes. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .2 mg/m3 DOE Short Term Exposure Limit .6 mg/m3 DOE Ceiling Limit 4 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM CHLORIDE CAS # 7447418 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 526.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX 2.1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Kidneys. Cardiovascular system. Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. Cyanosis and t-wave inversion have occurred in the breast-fed infants of women receiving lithium carbonate therapy. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents, Bromine trifluoride. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Lithium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26-36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 10 mg/m3 Immediately Dangerous to Life and Health 60 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM DIISOPROPYLAMIDE CAS # 4111540 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . I . . . NFPA HAZARD CODES (H,F,R,O) 3 4 2 W SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable FLASH POINT 10.4 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area Reacts violently in air Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC INCOMPATIBILITIES:Water, Strong oxidizing agents, Acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Lithium oxides Nitrogen oxides Store at 2-8C Keep tightly closed. Store in a cool dry place. Handle and store under nitrogen. Do not expose to ai Air sensitive. Moisture sensitive. Handle and store under inert gas. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure\. Container should be opened only by a technically qualified person. STORAGE: Keep tightly closed. Store in a cool dry place. Handle and store under nitrogen. Unsuitable: Do not expose to air and fire\. Incompatible Materials: Do not allow contact with water Store at 2-8%C SPECIAL REQUIREMENTS Air sensitive. Moisture sensitive. Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F-C Indication of Danger: Highly Flammable. Corrosive. R: 14-17-34 Risk Statements: Reacts violently with water. Spontaneously flammable in air. Causes burns. S: 16-26-36/37/39-43-45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of fire, use dry powder. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg.m3 DOE Short Term Exposure Limit 30 mg.m3 DOE Ceiling Limit 50 mg.m3 Immediately Dangerous to Life and Health 250 mg.m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM DODECYL SULFATE CAS # 2044566 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE The sodium salt of dodecyl sulfate has been reported to cause pulmonary sensitization resulting in hyperactive airway dysfunction and pulmonary allergy accompanied by fatigue, malaise, and aching. Significant symptoms of exposure can persist for more than two years and can be activated by a variety of nonspecific environmental stimuli such as automobile exhaust, perfumes, and passive smoking. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM FLUORIDE CAS # 7789244 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.5 - LD50 143.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX 2.5 - LC50 skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Kidneys. Cardiovascular system. Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Symptoms of exposure to inorganic fluorides may include salivation, nausea, vomiting, abdominal pain, fever, and labored breathing. Cyanosis and t-wave inversion have occurred in the breast-fed infants of women receiving lithium carbonate therapy. Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. Symptoms of fluoride overexposure may include salivation, nausea, vomiting, abdominal pain, fever, and labored breathing. Fluoride ion can reduce serum calcium levels possibly causing fatal hypocalcemia. Prolonged exposure to fluoride dusts, vapors, or mists results in perforation of the nasal septum. Chronic effects include excessive calcification of the bones, ligaments, and tendons. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Lithium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 32 36/37/38 Risk Statements: Toxic if swallowed. Contact with acids liberates very toxic gas. Irritating to eyes, respiratory system and skin. S: 22 26 36/37/39 45 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) Immediately Dangerous to Life and Health 250 mg/m US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 3.41 mg/m3 DOE Short Term Exposure Limit 10.2 mg/m3 DOE Ceiling Limit 17.1 mg/m3 Immediately Dangerous to Life and Health 341 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM HEXAFLUOROPHOSPHATE CAS # 21324403 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM HYDRIDE CAS # 7580678 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 3 2 2 W INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable Reacts violently in air Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Acids, Alcohols Reacts violently with water. FIRE EXTINGUISHER: Use approved class D extinguishers or smother with dry sand, dry ground limestone, or dry clay. Do not use water. Do not use carbon dioxide extinguisher on this material. Do not use dry chemical powder extinguishe TOXIC EMISSIONS WHEN BURNED: Liberates flammable/explosive hydrogen gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Handle and store under nitrogen. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 34 14 Risk Statements: Causes burns. Reacts violently with water. S: 16 26 27 36/37/39 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. Immediately Dangerous to Life and Health .5 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .025 mg/m3 DOE Short Term Exposure Limit .025 mg/m3 DOE Ceiling Limit .1 mg/m3 Immediately Dangerous to Life and Health .5 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM HYDROXIDE MONOHYDRATE CAS # 1310652 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 3 - LD50 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 6150.0 ROUTE OF EXPOSURE skin Contact: Causes severe burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Cardiovascular system. Central nervous system SIGNS AND SYMPTOMS OF EXPOSURE Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. Cyanosis and t-wave inversion have occurred in the breast-fed infants of women receiving lithium carbonate therapy. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): c - Inorganic Base/Oxidizer/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Lithium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. Incompatible Materials: Absorbs carbon dioxide from air\. SPECIAL REQUIREMENTS Store under inert gas. Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22-35 Risk Statements: Harmful if swallowed. Causes severe burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .05 mg/m3 DOE Short Term Exposure Limit .15 mg/m3 DOE Ceiling Limit 1 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM HYDROXIDE MONOHYDRATE CAS # 1310663 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 4 - LD50 210.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 960.0 ROUTE OF EXPOSURE skin Contact: Causes severe burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Cardiovascular system. Central nervous system SIGNS AND SYMPTOMS OF EXPOSURE Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. Cyanosis and t-wave inversion have occurred in the breast-fed infants of women receiving lithium carbonate therapy. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): c - Inorganic Base/Oxidizer/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Lithium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. Incompatible Materials: Absorbs carbon dioxide from air\. SPECIAL REQUIREMENTS Store under inert gas. Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22-35 Risk Statements: Harmful if swallowed. Causes severe burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .05 mg/m3 DOE Short Term Exposure Limit .15 mg/m3 DOE Ceiling Limit 1 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM HYDROXIDE MONOHYDRATE CAS # 64044515 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 10000.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 6150.0 ROUTE OF EXPOSURE skin Contact: Causes severe burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Cardiovascular system. Central nervous system SIGNS AND SYMPTOMS OF EXPOSURE Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. Cyanosis and t-wave inversion have occurred in the breast-fed infants of women receiving lithium carbonate therapy. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Lithium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. Incompatible Materials: Absorbs carbon dioxide from air\. SPECIAL REQUIREMENTS Store under inert gas. Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22-35 Risk Statements: Harmful if swallowed. Causes severe burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM IODIDE CAS # 10377512 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. Central nervous system. Kidneys. Eyes. Skin. SIGNS AND SYMPTOMS OF EXPOSURE Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms of exposure include: skin rash, running nose, headache and irritation of the mucous membrane. For severe cases the skin may show pimples, boils, hives, blisters and black and blue spots. Iodides are readily diffused across the placenta. Neonatal deaths from respiratory distress secondary to goiter have been reported. Iodides have been known to cause drug-induced fevers, which are usually of short duration. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents Incompatible with calomel, chloral hydrate, alkaloid salts, metallic salts, and potassium chlorate. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide Lithium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. Air sensitive. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM ISOPROPOXIDE CAS # 2388105 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of th mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Lithium hydroxide Lithium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Handle and store under nitrogen\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM LACTATE (D-) CAS # 27848813 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May cause irritation. May be harmful by inhalation, ingestion, or skin absorption. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C REACTIVE PROPERTIES STORAGE Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM LACTATE (L-) CAS # 27848802 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3620.7 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM MANGANESE OXIDE CAS # 12057179 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Men exposed to manganese dusts showed a decrease in fertility. Chronic manganese poisoning primarily involves the central nervous system. Early symptoms include languor, sleepiness and weakness in the legs. A stolid mask-like appearance of the face, emotional disturbances such as uncontrollable laughter and a spastic gait with tendency to fall in walking are findings in more advanced cases. High incidence of pneumonia has been found in workers exposed to the dust or fume of some manganese compounds. Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM METHOXIDE CAS # 865349 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 4 2 W INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Reacts violently in air Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Chlorinated solvents, Acids, Water. FIRE EXTINGUISHER: Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Lithium oxides REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water SPECIAL REQUIREMENTS Air and moisture sensitive. Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 14 17 34 Risk Statements: Reacts violently with water. Spontaneously flammable in air. Causes burns. S: 8 16 26 43 45 Safety Statements: Keep container dry. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of fire, use dry powder. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM NITRATE CAS # 7790694 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 1 0 1 OX SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. Cardiovascular system. Kidneys. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Cyanosis and t-wave inversion have occurred in the breast-fed infants of women receiving lithium carbonate therapy. Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids, Organic materials, Finely powdered metals, Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Lithium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Indication of Danger: Oxidizing. R: 8 Risk Statements: Contact with combustible material may cause fire. S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM PERCHLORATE CAS # 7791039 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 OX SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Material may be irritating to mucous membranes and upper respiratory tract Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Organic materials, Finely powdered metals. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Lithium oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xi Indication of Danger: Oxidizing. Irritant. R: 8 36/37/38 Risk Statements: Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. S: 17 26 3 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0005 mg/m3 DOE Short Term Exposure Limit .0015 mg/m3 DOE Ceiling Limit .01 mg/m3 Immediately Dangerous to Life and Health .06 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM PERCHLORATE TRIHYDRATE CAS # 13453786 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 1 OX ACUTE TOXICTY RISK INDEX 2.5 - LD50 1705.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Strong reducing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Lithium oxides Hydrogen chloride gas Store at 2-8C Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. Hygroscopic. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. Store at 2-8%C SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xi Indication of Danger: Oxidizing. Irritant. R: 8 36/37/38 Risk Statements: Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. S: 17 26 27 36/37/39 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM SULFATE CAS # 10377487 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 1 0 1 ACUTE TOXICTY RISK INDEX 2.9 - LD50 613.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Kidneys. Cardiovascular system. SIGNS AND SYMPTOMS OF EXPOSURE Lithium and its compounds are possible teratogens by analogy to lithium carbonate which has equivocal human teratogenic data and positive animal teratogenic data. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Lithium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .15 mg/m3 DOE Short Term Exposure Limit .5 mg/m3 DOE Ceiling Limit 3.5 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM TETRAFLUOROBORATE CAS # 14283079 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. Symptoms of fluoride overexposure may include salivation, nausea, vomiting, abdominal pain, fever, and labored breathing. Fluoride ion can reduce serum calcium levels possibly causing fatal hypocalcemia. Prolonged exposure to fluoride dusts, vapors, or mists results in perforation of the nasal septum. Chronic effects include excessive calcification of the bones, ligaments, and tendons. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong bases, Glass, Acids. FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Boron oxides Lithium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAG Suitable: Keep tightly closed. Store in a cool dry place\. Incompatible Materials: Avoid contact with acid. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 20/21/22 31 34 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Contact with acids liberates toxic gas. Causes burns. S: 22 26 27 36/37/39 45 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM TRIFLUOROMETHANE SULFONIMIDE CAS # 90076656 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be toxic by inhalation. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Nitrogen oxides Lithium oxides Hydrogen fluoride REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Handle and store under inert gas. Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 24/25-34-52/53 Risk Statements: Toxic in contact with skin and if swallowed. Causes burns. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 22-26-36/37/39-45-61 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LITHIUM TRIFLUOROMETHANESULFONATE CAS # 33454829 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Hydrogen fluoride Lithium oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LUCIFER YELLOW CAS # 67769475 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Store at 2-8C Hygroscopic. Keep container closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep container closed. Store in a cool dry place\. Store at 2-8%CSPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LUCIFERIN (D-) CAS # 2591175 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20%C SPECIAL REQUIREMENTS Air and light sensitive. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LUTETIUM OXIDE CAS # 12032201 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents Carbon dioxide. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: sture Materia REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LUTIDINE (2,3-) CAS # 583619 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 924.3 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 122 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 10 22 37/38 41 Risk Statements: Flammable. Harmful if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes. S: 16 26 39 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LUTIDINE (2,4-) CAS # 108474 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 3.1 - LD50 400.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.9 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Coughing, chest pains, difficulty in breathing. Gastrointestinal disturbances. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 10.9 mm Hg @ 20 C FLASH POINT 116.6 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Oxidizing agents, Chloroformates. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 10 23/24/25 36/37/38 Risk Statements: Flammable. Toxic by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 16 26 36/37/39 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .15 ppm DOE Short Term Exposure Limit .5 ppm DOE Ceiling Limit 4 ppm Immediately Dangerous to Life and Health 20 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LUTIDINE (2,6-) CAS # 108485 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 3 0 ACUTE TOXICTY RISK INDEX 3.1 - LD50 400.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.6 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Coughing, chest pains, difficulty in breathing. Gastrointestinal disturbances. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 4.0 mm Hg @ 20 C FLASH POINT 98.6 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Oxidizing agents, Chloroformates. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Do not breathe vapor. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 10 36/37/38 22 Risk Statements: Flammable. Irritating to eyes, respiratory system and skin. Harmful if swallowed. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 75 ppm DOE Short Term Exposure Limit 200 ppm DOE Ceiling Limit 1500 ppm Immediately Dangerous to Life and Health 7500 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LUTIDINEDIOL (2,6:ALPHA,2,5-) CAS # 42097427 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Nausea, dizziness, and headache. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Acid chlorides, Oxidizing agents, Chloroformates. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LUXOL FAST BLUE MBSN CAS # 1328514 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 2 OX INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE May cause nausea, vomiting, abdominal pain, gastrointestinal distress, diarrhea, respiratory congestion. The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Explosive Oxidizing Agent SEGREGATION: SHELF # 3 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide k - Explosive/Unstable WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 24/25 22 Safety Statements: Avoid contact with skin and eyes. Do not breathe dust. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LYCOPODIUM CAS # 68033709 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 16 Safety Statements: Keep away from sources of ignition - no smoking. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LYCOPODIUM CAS # 8023709 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 16 Safety Statements: Keep away from sources of ignition - no smoking. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LYSINE (DL-) CAS # 70542 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LYSINE (L-) CAS # 657272 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 10000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LYSINE ACETATE (L-) CAS # 57282492 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 11400.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LYSINE DIHYDROCHLORIDE (L-) CAS # 657261 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLIN User Exposure: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LYSINE HYDRATE (L:1-) CAS # 56871 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LYSINE HYDROCHLORIDE (N-EPSILON,2,4-DNP) CAS # 14401106 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Chlorine and nitrogen oxides Store at -20C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LYSOPHOSPHATIDYLCHOLINE (L,ALPHA-) CAS # 9008304 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides Store at -20C Air and light sensitive. Store under inert gas. Keep tightly closed. Store under argon. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under argon\. Store at -20C SPECIAL REQUIREMENTS Air and light sensitive. Store under inert gas. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LYSOZYME CAS # 12650883 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . F G . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fire conditions. Store at -20C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LYSOZYME CAS # 867550 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2100.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. LYXOSE (D-) CAS # 1114347 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep container closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. CF %o(&.1$79@DCKAGGI>QSu]_gio-r{q~ߊhnQh%CJOJQJ^J hnQh%\CD S T  . 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