ࡱ>    bjbj΀  ((kkkkk, E_ _ _ _ _ :!:!:!AAAAAAA$UGIZAk:!:!:!:!:!Akk_ _ eEnAnAnA:!j k_ k_ AnA:!AnAnAnA_ &P-& nAA{E0EnAQJ8QJnAQJknA<:!:!nA:!:!:!:!:!AAnA:!:!:!E:!:!:!:!QJ:!:!:!:!:!:!:!:!:!( 1: IBUPROFEN CAS # 15687271 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K L NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 636.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Clinical trials have shown the following possible adverse reactions: gastrointestinal disturbances including nausea, vomiting, cramps, diarrhea, constipation, bloating, central nervous system effects which include dizziness, headache, depression, insomnia, aseptic meningitis, somnolence, dermatological effects of maculopapular and vesiculobullous eruptions, urticaria, alopecia, erythema multiforme, stevens-johnson syndrome, hematologic effects of neutropenia, aplastic and hemolytic anemia, thrombocytopenia, decreases in hemoglobin and hematocrit. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 36 Safety Statements: Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IBUPROFEN SODIUM CAS # 31121934 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K L NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 636.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMIDAZOLE CAS # 288324 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 3 1 2 ACUTE TOXICTY RISK INDEX 3.4 - LD50 220.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Intraperitoneal Rat 2804 MG/KG Intraperitoneal Mouse 468 MG/KG LD50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible Explosive FLASH POINT 293 F Forms explosive unstable peroxides Test periodically or discard SEGREGATION: SHELF # 3 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam\. Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits t REACTIVE PROPERTIES User Exposure: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 Risk Statements: Harmful if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4 mg/m3 DOE Short Term Exposure Limit 12.5 mg/m3 DOE Ceiling Limit 75 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMIDAZOLECARBOXALDEHYDE (4,5-) CAS # 3034502 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Ammonia Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMIDAZOLECARBOXYLIC ACID (4-) CAS # 1072840 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMIDAZOLIDINETHIONE (2-) CAS # 96457 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX A B . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.8 - TD50 8.1 mg/Kg HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 3.8 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1832.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Liver. Thyroid. Pituitary. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 61 22 Risk Statements: May cause harm to the unborn child. Also harmful if swallowed. S: 53 45 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .75 mg/m3 DOE Short Term Exposure Limit 2.5 mg/m3 DOE Ceiling Limit 15 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMIDAZOLYL PHENOL (4:1-) CAS # 10041028 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMIDAZOLYLBENZOIC ACID (4,1H:1-) CAS # 17616045 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMINOBISPROPYLAMINE (3,3'-) CAS # 56188 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . G . . J K L NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 5 - LD50 738.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 30.0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be fatal if absorbed through skin. Eye Contact: Causes burns. Inhalation: Highly toxic by inhalation. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause skin sensitization SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 242.6 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. Do not breathe vapor. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T+ C Indication of Danger: Very toxic. Corrosive. R: 22 24 26 35 43 Risk Statements: Harmful if swallowed. Toxic in contact with skin. Very toxic by inhalation. Causes severe burns. May cause sensitization by skin contact. S: 26 28 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap-suds. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .6 ppm DOE Short Term Exposure Limit 1.5 ppm DOE Ceiling Limit 12.5 ppm Immediately Dangerous to Life and Health 60 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMINODIACETIC ACID CAS # 11139858 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMINODIACETIC ACID CAS # 142734 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1 mg/m3 DOE Short Term Exposure Limit 3 mg/m3 DOE Ceiling Limit 20 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMINODIACETIC ACID CAS # 68131044 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2 mg/m3 DOE Short Term Exposure Limit 6 mg/m3 DOE Ceiling Limit 40 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMINODIACETONITRILE CAS # 628875 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 710.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES User Exposure: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMINODIBENZYL CAS # 494199 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMINORTHYLETHYL LYSINE HYDROCHLORIDE CAS # 150403897 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store with desiccant. Store at 2-8%C SPECIAL REQUIREMENTS Very hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMINOSTILBENE CAS # 256962 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: N-Xn Indication of Danger: Dangerous for the environment. Harmful. R: 51/53-22 Risk Statements: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful if swallowed. S: 61 Safety Statements: Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IMIPRAMINE HYDROCHLORIDE CAS # 113520 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I J K L NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 305.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Heart. Blood. Endocrine system. SIGNS AND SYMPTOMS OF EXPOSURE Adverse reactions: orthostatic hypotension, hypertension, tachycardia, palpitation, myocardial infarction, arrhythmias, heart block, precipitation of congestive heart failure, stroke, hallucinations, disorientation, delusions, anxiety, restlessness, agitation, insomnia, hypomania, numbness, tingling, paresthesias of extremities, ataxia, tremors, incoordination, peripheral neuropathy, seizures, tinnitus, blurred vision, mydriasis, constipation, paralytic ileus, urinary retention, skin rash, petechiae, urticaria, photosensitization, edema, nausea, vomiting, anorexia, epigastric distress, diarrhea, stomatitis, abdominal cramps, black tongue, bone marrow depression, agranulocytosis, purpura, eosinophilia, alopecia, and proneness to falling. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDANDIONE (1,3-) CAS # 606235 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDANONE (1-) CAS # 83330 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235.4 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin andclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDAZOLE CAS # 271443 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 OX INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDENE CAS # 95136 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 14000.0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. Lungs. Gallbladder. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 136.4 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 10 65 Risk Statements: Flammable. Harmful: may cause lung damage if swallowed. S: 23 24/25 62 Safety Statements: Do not breathe vapor. Avoid contact with skin and eyes. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 10 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 5 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 ppm DOE Short Term Exposure Limit 10 ppm DOE Ceiling Limit 60 ppm Immediately Dangerous to Life and Health 300 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDIGO CAS # 482893 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX .7 - LD50*** mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDIGO CARMINE CAS # 860220 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 36 Safety Statements: Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 20 mg/m3 DOE Short Term Exposure Limit 60 mg/m3 DOE Ceiling Limit 75 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDIUM CAS # 7440746 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if inhaled or swallowed. Causes irritation. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .010000 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Sulfur, Strong acids. FIRE EXTINGUISHER: Sand or dry powder type agents specially designed formetal powder fires. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/3 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .1 mg/m3 DOE Short Term Exposure Limit .1 mg/m3 DOE Ceiling Limit .6 mg/m3 Immediately Dangerous to Life and Health 3.5 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDIUM(I) CHLORIDE CAS # 13465106 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDIUM(III) BROMIDE CAS # 13465093 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Damage to the kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen bromide gas Indium/indium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Handle and store under nitrogen\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDIUM(III) CHLORIDE CAS # 10025828 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Heart. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Indium salts are relatively nontoxic when administered orally; they are highly toxic when administered subcutaneously or intravenously to experimental animals. When injected into experimental animals, indium has caused adverse effects on the blood, heart, liver, and kidneys, but these have NOT been seen in occupationally exposed humans. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 Risk Statements: Harmful if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .193 mg/m3 DOE Short Term Exposure Limit .578 mg/m3 DOE Ceiling Limit 1 mg/m3 Immediately Dangerous to Life and Health 1 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDIUM(III) HYDROXIDE CAS # 20661216 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .010000 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids Carbon dioxide. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Incompatible Materials: Absorbs carbon dioxide from air. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDOLE CAS # 120729 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 1000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Nausea, headache, and vomiting. Exposure can cause: PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 249.8 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents Iron and iron salts. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Water spray. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air and light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn-N Indication of Danger: Harmful. Dangerous for the environment. R: 21/22-37/38-41-50/53 Risk Statements: Harmful in contact with skin and if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26-36/37/39-60-61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDOLE BORONIC ACID (1-N-BOC:2-) CAS # 213318446 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Borane/boron oxides Store at -20C Handle and store under inert gas. Light sensitive. Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20%C SPECIAL REQUIREMENTS Handle and store under inert gas. Light sensitive. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDOLE CARBOXAMIDE (1H:5-) CAS # 1670877 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDOLE CARBOXAMIDE (5-) CAS # 1196696 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 1 OX INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDOLE CARBOXYLIC ACID (2-) CAS # 1477505 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDOLE CARBOXYLIC ACID (5-) CAS # 1670811 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at -20C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store at -20%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDOLE CARBOXYLIC ACID (6-) CAS # 1670822 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 24/25 22 Safety Statements: Avoid contact with skin and eyes. Do not breathe dust. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDOLE GLYOXYLIC ACID (3-) CAS # 1477492 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Store at 2-8%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDOLEALDEHYDE (3-) CAS # 487898 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong reducing agents. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Water spray. REACTIVE PROPERTIES HANDLING: Use protective clothing, gloves, and mask. Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep container closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .75 ppm DOE Short Term Exposure Limit 2.5 ppm DOE Ceiling Limit 15 ppm Immediately Dangerous to Life and Health 75 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDOLEBUTYRIC ACID CAS # 133324 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 322.6 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 36/37/38 Risk Statements: Toxic if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDOLEPROPIONIC ACID (3-) CAS # 830966 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at -20C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDOLEPYRUVIC ACID (3-) CAS # 392121 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDOLYLACETIC ACID (3-) CAS # 87514 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 REPRODUCTIVE RISK INDEX 2.5 ACUTE TOXICTY RISK INDEX 3 - LD50 500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: IDE NITROGEN OXIDES REACTIVE PROPERTIES MINOR AMOUNTS OF ACID CAUSE ACROLEIN TO POYLMERIZE WITH RELEASE OF HEAT.BENZYL ALCOHOL CONTAINING ACIDIC CONSTITUENTS AND DISSOLVED IRON WAS FOUND TOPOLYMERIZE WITH A RAPID TEMPERATURE INCREASE WHEN HEATED IN EXCESS OF100C.(AMINES, PYRIDINE, AND ALKALI HYDROXIDES ACT AS INHIBITORS AND PREVENTPOLYMERIZATION.) REACT VIGOROUSLY WITH LITHIUM ALUMINUM HYDRIDE. HIGHCONCENTRATIONS OF ACID REACT EXPLOSIVELY WITH NICKEL NITRIDE AND HEAT.INITIATE A FAST DECOMPOSITION OF SODIUM OZONATE. REACTS WITH THORIUMPHOSPHIDE TO RELEASE SPONTANEOUSLY FLAMMABLE PHSOPHINE. REACTS VIOLENTLY WITHTRI-ISO-BUTYL ALUMINUM. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INDOMETHACIN CAS # 53861 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX A . C . . . . . . . K . NFPA HAZARD CODES (H,F,R,O) 3 1 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 4.6 - TD50 1.2 mg/Kg EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 5+ - LD50 2.4 mg/Kg INHALATION RISK INDEX <1 - LC50 skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and Ingestion: May be fatal if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Oral Man 15 mg/kg Remarks: Blood:Aplastic anemia. Oral Rat LD50 Remarks: Gastrointestinal:Ulceration or bleeding from stomach. Intraperitoneal 13 MG/KG LD50 Subcutaneous Rat LD50 Intravenous Rat LD50 Intramuscular Rat 26300 UG/KG LD50 Rat 31900 UG/KG LD50 Mouse 11.841 mg/kg LD50 Mouse 10 MG/KG LD50 Subcutaneous 18300 UG/KG LD50 Intravenous 30 MG/KG LD50 Intramuscular 18200 UG/KG LD50 Oral 160 mg/kg LD50 Intravenous Dog LD50 Oral Cat LD50 Oral Rabbit 135 mg/kg LD50 Guinea pig 100 mg/kg LD50 Guinea pig 143 MG/KG LD50 Guinea pig 180 MG/KG LD50 Oral 81 mg/kg LD50 Oral 8 mg/kg LD50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 233.6 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Store at 2-8C REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE Store at 2-8%C SPECIAL REQUIREMENTS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INOSINE CAS # 58639 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 10000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INOSITOL CAS # 87898 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.4 - LD50 17241.4 mg/Kg INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: IDE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INSULIN CAS # 11070738 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Store at -20C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INSULIN CHAIN B OXIDIZED CAS # 30003726 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8%C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INULIN CAS # 9005805 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. INVERTASE CAS # 9001574 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODIC ACID CAS # 7782685 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 OX INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed TARGET ORGAN(S) OR SYSTEM(S) Thyroid. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms of exposure include: skin rash, running nose, headache and irritation of the mucous membrane. For severe cases the skin may show pimples, boils, hives, blisters and black and blue spots. Iodides are readily diffused across the placenta. Neonatal deaths from respiratory distress secondary to goiter have been reported. Iodides have been known to cause drug-induced fevers, which are usually of short duration. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Reducing agents, Alcohols, Organic materials. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O C Indication of Danger: Oxidizing. Corrosive. R: 8 34 Risk Statements: Contact with combustible material may cause fire. Causes burns. S: 17 26 36/37/39 45 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .139 mg/m3 DOE Short Term Exposure Limit .139 mg/m3 DOE Ceiling Limit .139 mg/m3 Immediately Dangerous to Life and Health 2.77 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODINE CAS # 7553562 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . B . . E . G . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 3.5 ACUTE TOXICTY RISK INDEX 1.5 - LD50 14000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes burns. Severe lachrymator. Inhalation: Harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. Kidneys. Endocrine system. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms of exposure include: skin rash, running nose, headache and irritation of the mucous membrane. For severe cases the skin may show pimples, boils, hives, blisters and black and blue spots. Iodides are readily diffused across the placenta. Neonatal deaths from respiratory distress secondary to goiter have been reported. Iodides have been known to cause drug-induced fevers, which are usually of short duration. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .250 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Rubber, Plastics Iron and iron salts., Sulfur, Ammonia, Magnesium, Zinc, Aluminum, Metals Alkalies, antimony salts, arsenites, bromides, carbonates, chlorides, iodides, thiocyanates, ferrous salts, hypophosphites, morphine salts, oils, creosot REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Handle and store under inert gas. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn N Indication of Danger: Harmful. Dangerous for the environment. R: 20/21 50 Risk Statements: Harmful by inhalation and in contact with skin. Very toxic to aquatic organisms. S: 23 25 61 Safety Statements: Do not breathe vapor. Avoid contact with eyes. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 2 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .1 ppm DOE Short Term Exposure Limit .1 ppm DOE Ceiling Limit .5 ppm Immediately Dangerous to Life and Health 5 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODINE MONOBROMIDE CAS # 7789335 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. Eyes. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Exposure can cause: Damage to the eyes. Dermatitis. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Phosphorus, Alcohols, Forms explosive mixtures with:, Sodium, Potassium. TOXIC EMISSIONS WHEN BURNED: Hydrogen bromide gas Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air, light, and moisture sensitive. Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODINE MONOCHLORIDE CAS # 7790990 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. Kidneys. Endocrine system. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Organic materials, Strong bases, Metals. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Hydrogen iodide Store at 2-8C Explodes on contact with potassium, while a mixture with sodium explodes only on impact. Aluminum foil ignites only after prolonged contact. On mixing with phosphorous trichloride, an inten REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Incompatible Materials: Iodine monochloride explodes on contact with potassium, while a mixture with sodium explodes only on impact. Aluminum foil ignites only after prolonged contact. On mixing with phosphorous trichloride, an intensely exothermic reaction occurs. Store at 2-8%C SPECIAL REQUIREMENTS Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 42 Risk Statements: Causes burns. May cause sensitization by inhalation. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODINE TRICHLORIDE CAS # 865441 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 OX INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Phosphorus, Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Hydrogen iodide Store at -20C Keep tightly closed. Do not store near, nor allow contact with, clothing and other combustible mater REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. Open carefully. STORAGE: Keep tightly closed. Unsuitable: Do not store near, nor allow contact with, clothing and other combustible material. Store at -20%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOACETAMIDE CAS # 144489 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 3.3 - LD50 238.7 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Sensitization: May cause allergic reaction. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong bases, Strong oxidizing agents, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide Store at 2-8C Keep tightly closed. Store with desiccant. Light sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store with desiccant\. Store at 2-8%C SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 42/43 Risk Statements: Toxic if swallowed. May cause sensitization by inhalation and skin contact. S: 22 36/37 45 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOACETIC ACID CAS # 64697 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. Causes blisters on contact with skin. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Symptoms may be delayed. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 6.4 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong reducing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide Store at -20C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T C Indication of Danger: Toxic. Corrosive. R: 25 35 Risk Statements: Toxic if swallowed. Causes severe burns. S: 22 36/37/39 45 Safety Statements: Do not breathe dust. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOACETONITRILE CAS # 624759 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Lachrymator. Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 186.8 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Strong oxidizing agents, Strong bases, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides Hydrogen iodide REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22-34 Risk Statements: Harmful if swallowed. Causes burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOACETOPHENONE (4'-) CAS # 13329403 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOANILINE (2-) CAS # 615430 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to respiratory system and skin. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOANILINE (4-) CAS # 540374 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 523.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. Multiple Routes: Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOBENZALDEHYDE (4-) CAS # 15164440 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide Store at 2-8C Keep tightly closed. Air and light sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8%C SPECIAL REQUIREMENTS Air and light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 36 26 Safety Statements: Wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOBENZENE CAS # 591504 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 2 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1749.0 mg/Kg INHALATION RISK INDEX 1.6 - LC50 17000.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, an toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .774 mm Hg @ 20 C FLASH POINT 170.6 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Magnesium, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36 Risk Statements: Harmful if swallowed. Irritating to eyes. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 75 mg/m3 DOE Short Term Exposure Limit 200 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOBENZOIC ACID (3-) CAS # 618519 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4290.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOBENZOIC ACID (4-) CAS # 619589 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLIN User Exposure: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOBENZOIC ACID (ORTHO-) CAS # 88675 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . K L NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 4838.7 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. SENSITIZATION Sensitization: May cause allergic reaction. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms of exposure include: skin rash, running nose, headache and irritation of the mucous membrane. For severe cases the skin may show pimples, boils, hives, blisters and black and blue spots. Iodides are readily diffused across the placenta. Neonatal deaths from respiratory distress secondary to goiter have been reported. Iodides have been known to cause drug-induced fevers, which are usually of short duration. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. TOXIC EMISSIONS WHEN BURNED: Iodine Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOBENZOYL CHLORIDE (4-) CAS # 1711020 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOBENZYL ALCOHOL (4-) CAS # 18282514 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOBENZYL BROMIDE (3-) CAS # 49617836 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen bromide gas Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 22 26 27 36/37/39 45 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOBENZYLAMINE HYDROCHLORIDE (3-) CAS # 3718885 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Hydrogen iodide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOBUTANE (1-) CAS # 542698 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 3 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 3 - LD50 mg/Kg INHALATION RISK INDEX <1 - LC50 6100.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 92 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water may be effective for cooling, but may not effect extinguishment. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 10 20 Risk Statements: Flammable. Harmful by inhalation. S: 16 36 Safety Statements: Keep away from sources of ignition - no smoking. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOBUTYL ACETATE (4-) CAS # 40596449 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 195 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODODIMETHYL URACIL (5:1,3:1H-) CAS # 40738838 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . K L NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms of exposure include: skin rash, running nose, headache and irritation of the mucous membrane. For severe cases the skin may show pimples, boils, hives, blisters and black and blue spots. Iodides are readily diffused across the placenta. Neonatal deaths from respiratory distress secondary to goiter have been reported. Iodides have been known to cause drug-induced fevers, which are usually of short duration. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 42/43 63 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. May cause sensitization by inhalation and skin contact. Possible risk of harm to the unborn child. S: 22 26 36/37/39 45 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODODODECANE (1-) CAS # 4292197 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 230 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOETHANE CAS # 75036 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 2 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 330.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 3.7 - LC50 65000.0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Causes blisters on contact with skin. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Kidneys. Liver. Thyroid. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Exposure can cause: Narcotic effect. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 106.4 mm Hg @ 20 C FLASH POINT 161 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Magnesium, Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Iodine Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20-36/37/38-42/43 Risk Statements: Harmful by inhalation. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact. S: 23-26-36/37-45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 ppm DOE Short Term Exposure Limit 15 ppm DOE Ceiling Limit 100 ppm Immediately Dangerous to Life and Health 500 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOETHANOL (2-) CAS # 624760 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 3 2 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4 - LD50 50.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 149 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acid anhydrides, Acid chlorides, Phosphorus halides, Strong acids, Strong oxidizing agents, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide Store at 2-8C Keep tightly closed. Keep away from heat and open flame. Light sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid prolonged or repeated exposure. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store at 2-8%C SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 45 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOFORM CAS # 75478 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . I J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.1 - LD50 355.0 mg/Kg NEUROTOXIC - RISK INDEX 2.0 INHALATION RISK INDEX <1 - LC50 2651.7 skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea, headache, and vomiting. May cause dermatitis, restlessness, weakness, headache, confusion, rapid heartbeat, and central nervous system depression. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Alkali metals, Strong bases, Strong oxidizing agents, Magnesium. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit .6 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value .6 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOHEXANE (1-) CAS # 638459 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . G . . . . L NFPA HAZARD CODES (H,F,R,O) 3 2 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1800.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 142 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. Do not breathe vapor. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn N Indication of Danger: Harmful. Dangerous for the environment. R: 22 37/38 41 43 51/53 Risk Statements: Harmful if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes. May cause sensitization by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 36/37/39 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOINDOLE (5-) CAS # 16066914 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 36 26 Safety Statements: Wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOISATIN (5-) CAS # 20780761 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 3.1 - LD50 420.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. Sensitization: Strong sensitizer. skin: May cause skin sensitization SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light and moisture sensitive. Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 43 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOMETHANE CAS # 74884 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . G . I J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 4 - LD50 76.0 mg/Kg NEUROTOXIC - RISK INDEX 2.0 INHALATION HAZARD INHALATION RISK INDEX 4.6 - LC50 1550.0 ROUTE OF EXPOSURE skin Contact: Causes blisters on contact with skin. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes burns. Inhalation: Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Liver. Kidneys. Thyroid. Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea, dizziness, and headache. Blurred vision. Weakness. Drowsiness. Ataxia. Confusion. Convulsions. Narcotic effect. Pulmonary edema. Effects may be delayed. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms of exposure include: skin rash, running nose, headache and irritation of the mucous membrane. For severe cases the skin may show pimples, boils, hives, blisters and black and blue spots. Iodides are readily diffused across the placenta. Neonatal deaths from respiratory distress secondary to goiter have been reported. Iodides have been known to cause drug-induced fevers, which are usually of short duration. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid VAPOR PRESSURE 407.9 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 21 23/25 37/38 40 Risk Statements: Harmful in contact with skin. Toxic by inhalation and if swallowed. Irritating to respiratory system and skin. Limited evidence of a carcinogenic effect. S: 36/37 38 45 Safety Statements: Wear suitable protective clothing and gloves. In case of insufficient ventilation, wear suitable respiratory equipment. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 2 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 2 ppm Immediately Dangerous to Life and Health 100 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 ppm DOE Short Term Exposure Limit 25 ppm DOE Ceiling Limit 50 ppm Immediately Dangerous to Life and Health 125 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOMETHANE-D CAS # 865509 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . G . I J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 4 - LD50 76.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX 4.6 - LC50 1550.0 ROUTE OF EXPOSURE skin Contact: Causes blisters on contact with skin. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes burns. Inhalation: Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Liver. Kidneys. Thyroid. Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea, dizziness, and headache. Blurred vision. Weakness. Drowsiness. Ataxia. Confusion. Convulsions. Narcotic effect. Pulmonary edema. Effects may be delayed. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms of exposure include: skin rash, running nose, headache and irritation of the mucous membrane. For severe cases the skin may show pimples, boils, hives, blisters and black and blue spots. Iodides are readily diffused across the placenta. Neonatal deaths from respiratory distress secondary to goiter have been reported. Iodides have been known to cause drug-induced fevers, which are usually of short duration. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid VAPOR PRESSURE 341.7 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. SPECIAL REQUIREMENTS Light sensitive. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 21 23/25 40 34 42/43 Risk Statements: Harmful in contact with skin. Toxic by inhalation and if swallowed. Limited evidence of a carcinogenic effect. Causes burns. May cause sensitization by inhalation and skin contact. S: 26 36/37/39 38 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of insufficient ventilation, wear suitable respiratory equipment. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 2 ppm Immediately Dangerous to Life and Health 100 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOMETHYL METHYL EITHER CAS # 13057197 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E F G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 72 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide Store at 2-8C Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Handle Light sensitive. Readily hydrolyzed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Handle and store under nitrogen. Store at 2-8%C SPECIAL REQUIREMENTS Light sensitive. Readily hydrolyzed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 10 23/24/25 34 40 Risk Statements: Flammable. Toxic by inhalation, in contact with skin and if swallowed. Causes burns. Limited evidence of a carcinogenic effect. S: 16 26 36/37/39 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOMETHYLPROPANE (1,2-) CAS # 513382 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. TOXICITY DAT Inhalation Rat 6,700 mg/m3 LC50 Intraperitoneal Rat 1241 MG/KG LD50 Intraperitoneal Mouse 594 MG/KG LD50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 20.0 mm Hg @ 20 C FLASH POINT 55 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water may be effective for cooling, but may not effect extinguishment. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not get in eyes, on skin, on clothing. Do not breathe vapor. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Xi Indication of Danger: Highly Flammable. Irritant. R: 11 36/37/38 Risk Statements: Highly flammable. Irritating to eyes, respiratory system and skin. S: 16 26 36 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOMETHYLTRIMETHYLSILANE CAS # 4206671 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 84.2 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silicon oxide Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 10 36/37/38 Risk Statements: Flammable. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODONITROBENZENE (1:4-) CAS # 636986 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Absorption: Skin absorption may occur. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 212 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong bases, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODONITROBENZENE (2-) CAS # 609734 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong bases, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODONITROTETRAZOLIUM FORMAZAN CAS # 7781499 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODONITROTETRAZOLIUM VIOLET (PARA-) CAS # 146689 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOOCTANE (1-) CAS # 629276 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .181 mm Hg @ 20 C FLASH POINT 188.6 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, andclothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOPHENOL (2-) CAS # 533584 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms of exposure include: skin rash, running nose, headache and irritation of the mucous membrane. For severe cases the skin may show pimples, boils, hives, blisters and black and blue spots. Iodides are readily diffused across the placenta. Neonatal deaths from respiratory distress secondary to goiter have been reported. Iodides have been known to cause drug-induced fevers, which are usually of short duration. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOPHENOL (3-) CAS # 626028 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 9354.8 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Lachrymator. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOPHENOL (4-) CAS # 540385 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms of exposure include: skin rash, running nose, headache and irritation of the mucous membrane. For severe cases the skin may show pimples, boils, hives, blisters and black and blue spots. Iodides are readily diffused across the placenta. Neonatal deaths from respiratory distress secondary to goiter have been reported. Iodides have been known to cause drug-induced fevers, which are usually of short duration. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 21/22 34 Risk Statements: Harmful in contact with skin and if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOPROPANE (1-) CAS # 107084 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 1 ACUTE TOXICTY RISK INDEX 1.9 - LD50 5806.5 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.4 - LC50 73000.0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 34.4 mm Hg @ 20 C FLASH POINT 112 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 10 20 36/37/38 Risk Statements: Flammable. Harmful by inhalation. Irritating to eyes, respiratory system and skin. S: 16 26 36/37 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOPROPANE (2-) CAS # 75309 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 55.5 mm Hg @ 20 C FLASH POINT 108 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide Store at 2-8C Keep tightly closed. Keep away from heat and open flame. REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 16 Safety Statements: Keep away from sources of ignition - no smoking. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOPROPANOL (3:1-) CAS # 627327 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOPROPIONIC ACID (3-) CAS # 141764 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 27 28 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOSALICYLALDEHYDE (5-) CAS # 1761622 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOSOBENZOIC ACID (2-) CAS # 304916 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 196.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide Store at -20C Keep tightly closed. Store under nitrogen. Air and light sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store under nitrogen\. Store at -20%C SPECIAL REQUIREMENTS Air and light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOSUCCINIMIDE CAS # 516121 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Light and moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOTRIFLUOROETHANE (2:1,1,1-) CAS # 353833 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid VAPOR PRESSURE 204.7 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IODOTRIMETHYLSILANE CAS # 16029984 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 4 1 W INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT -23.8 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC INCOMPATIBILITIES:Strong acids, Strong bases, Strong oxidizing agents Reacts violently with water. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Silicon oxide Hydrogen iodide Store at -20C Handle and store under inert gas. Keep tightly closed. Keep away from heat, sparks, and open flame. Do not allow water to enter contai REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Unsuitable: Do not allow water to enter container. Store at -20%C SPECIAL REQUIREMENTS Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 14 34 Risk Statements: Highly flammable. Reacts violently with water. Causes burns. S: 16 26 36/37/39 43 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of fire, use dry powder. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IRIDIUM CAS # 7439885 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 3 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Halogens, Tin/tin oxides, Lead, Zinc. FIRE EXTINGUISHER: Dry chemical powder. TOXIC EMISSIONS WHEN BURNED: Iridium oxides REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Xi Indication of Danger: Highly Flammable. Irritant. R: 36 Risk Statements: Irritating to eyes. S: 16 26 36/37/39 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 6 mg/m3 DOE Short Term Exposure Limit 20 mg/m3 DOE Ceiling Limit 125 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IRON (III) CHLORIDE TETRAHYDRATE CAS # 13478109 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 984.0 mg/Kg INHALATION RISK INDEX 1.4 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Overdose of iron compounds may have a corrosive effect on the gastrointestinal mucosa and be followed by necrosis, perforation, and stricture formation. Several hours may elapse before symptoms that can include epigastric pain, diarrhea, vomiting, nausea, and hematemesis occur. After apparent recovery a person may experience metabolic acidosis, convulsions, and coma hours or days later. Further complications may develop leading to acute liver necrosis that can result in death due to hepatic coma. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .290 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Forms explosive mixtures with:, Potassium, Sodium. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Iron oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air sensitive. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-38-41 Risk Statements: Harmful if swallowed. Irritating to skin. Risk of serious damage to eyes. S: 26-39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 3.56 mg/m3 DOE Short Term Exposure Limit 3.56 mg/m3 DOE Ceiling Limit 7.5 mg/m3 Immediately Dangerous to Life and Health 40 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IRON(II) ACETATE CAS # 3094879 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Damage to the lungs. Overdose of iron compounds may have a corrosive effect on the gastrointestinal mucosa and be followed by necrosis, perforation, and stricture formation. Several hours may elapse before symptoms that can include epigastric pain, diarrhea, vomiting, nausea, and hematemesis occur. Afte apparent recovery a person may experience metabolic acidosis, convulsions, and coma hours or days later. Further complications may develop leading to acute liver necrosis that can result in death due to hepatic coma. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Handle and store under nitrogen\. SPECIAL REQUIREMENTS Handle and store under inert gas. Air sensitive. Moisture sensitive. Air and moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IRON(II) SULFATE CAS # 7782630 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 4903.2 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) G.I. System. Liver. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 11.7 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Iron oxides Sulfur oxides Store at 2-8C Air and moisture sensitive. Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8%C SPECIAL REQUIREMENTS Air and moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 36/37/39 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4.98 mg/m3 DOE Short Term Exposure Limit 14.9 mg/m3 DOE Ceiling Limit 25 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. IRON(III) BROMIDE CAS # 10031262 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Potassium, Sodium. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen\. Incompatible Materials: Protect from moisture\. SPECIAL REQUIREMENTS Store under inert gas. Very hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISATIN CAS # 91565 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISATOIC ANHYDRIDE CAS # 118489 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E F G . . . . L NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 586.4 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 43 Risk Statements: Irritating to eyes. May cause sensitization by skin contact. S: 24 26 37 Safety Statements: Avoid contact with skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISETHIONIC ACID SODIUM CAS # 1562001 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOAMYL ACETATE CAS # 123922 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 3 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 16600.0 mg/Kg INHALATION RISK INDEX 1.4 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid VAPOR PRESSURE 4.0 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Oxidizing agents, Strong acids, Strong bases, Reducing agents. FIRE EXTINGUISHER: foam. Unsuitable: Water may be effective for cooling, but may not effect extinguishment\. Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Do STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 immediately with plenty of water and seek medical advice. Wear suitable protective clothing. Immediately Dangerous to Life and Health 1000 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 100 ppm DOE Short Term Exposure Limit 100 ppm DOE Ceiling Limit 200 ppm Immediately Dangerous to Life and Health 1000 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOAMYL NITRITE CAS # 110463 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E F G . . J K L NFPA HAZARD CODES (H,F,R,O) 3 3 0 ACUTE TOXICTY RISK INDEX 3 - LD50 505.0 mg/Kg INHALATION RISK INDEX <1 - LC50 2119.7 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Blood. Smooth muscle. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation of vapors may cause a sharp decrease in blood pressure with resulting loss of consciousness. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT -4 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC CORROSIVE INCOMPATIBILITIES:Oxidizing agents, Alcohols. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Nitrites Store at 2-8C Air, light, and moisture sensitive. Handle and store under inert gas. Keep container closed. Keep away from heat, sparks, and open flame. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame\. Store at 2-8%C SPECIAL REQUIREMENTS Air, light, and moisture sensitive. Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F Xn Indication of Danger: Highly Flammable. Harmful. R: 11 20/22 Risk Statements: Highly flammable. Harmful by inhalation and if swallowed. S: 16 24 46 Safety Statements: Keep away from sources of ignition - no smoking. Avoid contact with skin. If swallowed, seek medical advice immediately and show this container or label. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 3 ppm DOE Short Term Exposure Limit 7.5 ppm DOE Ceiling Limit 60 ppm Immediately Dangerous to Life and Health 300 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOASCORBIC ACID (D-) CAS # 89656 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: SIUM COPPER HAZARDOUS COMBUSTION OR DECOMPO REACTIVE PROPERTIES MINOR AMOUNTS OF ACID CAUSE ACROLEIN TO POYLMERIZE WITH RELEASE OF HEAT.BENZYL ALCOHOL CONTAINING ACIDIC CONSTITUENTS AND DISSOLVED IRON WAS FOUND TOPOLYMERIZE WITH A RAPID TEMPERATURE INCREASE WHEN HEATED IN EXCESS OF100C.(AMINES, PYRIDINE, AND ALKALI HYDROXIDES ACT AS INHIBITORS AND PREVENTPOLYMERIZATION.) REACT VIGOROUSLY WITH LITHIUM ALUMINUM HYDRIDE. HIGHCONCENTRATIONS OF ACID REACT EXPLOSIVELY WITH NICKEL NITRIDE AND HEAT.INITIATE A FAST DECOMPOSITION OF SODIUM OZONATE. REACTS WITH THORIUMPHOSPHIDE TO RELEASE SPONTANEOUSLY FLAMMABLE PHSOPHINE. REACTS VIOLENTLY WITHTRI-ISO-BUTYL ALUMINUM. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOBUTANOL CAS # 78831 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . I . . L NFPA HAZARD CODES (H,F,R,O) 1 3 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2460.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX 2.2 - LC50 24202.4 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Causes dermatitis. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Can cause CNS depression. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 8.0 mm Hg @ 20 C FLASH POINT 82.4 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Carbon Dioxide, dry chemical powder, or appropriate foam. Water can be applied as a spray or fog and if properly applied is capable of extinguishing the fire by REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: X Indication of Danger: Irritant. R: 10 37/38 41 67 Risk Statements: Flammable. Irritating to respiratory system and skin. Risk of serious damage to eyes. Vapors may cause drowsiness and dizziness. S: 7/9 13 26 37/39 46 Safety Statements: Keep container tightly closed and in well-ventilated place. Keep away from food, drink, and animal feedingstuffs. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. If swallowed, seek medical advice immediately and show this container or label. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 50 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 50 ppm Immediately Dangerous to Life and Health 1600 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 100 ppm DOE Short Term Exposure Limit 1250 ppm DOE Ceiling Limit 1600 ppm Immediately Dangerous to Life and Health 1600 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOBUTYL ACETATE CAS # 110190 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 3 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 13400.0 mg/Kg INHALATION RISK INDEX 1.9 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Vapor or mist is irritating to the eyes. Inhalation: Vapor or mist is irritating to the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 15.0 mm Hg @ 20 C FLASH POINT 71 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. FIREFIGHTIN Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): F REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 66 Risk Statements: Highly flammable. Repeated exposure may cause skin dryness or cracking. S: 16 23 25 29 3 Safety Statements: Keep away from sources of ignition - no smoking. Do not breathe vapor. Avoid contact with eyes. Do not empty into drains. Take precautionary measures against static discharges. Immediately Dangerous to Life and Health 1300 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 150 ppm DOE Short Term Exposure Limit 150 ppm DOE Ceiling Limit 250 ppm Immediately Dangerous to Life and Health 1300 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOBUTYL CHLOROFORMATE CAS # 543271 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . G . . . . L NFPA HAZARD CODES (H,F,R,O) 3 3 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Lachrymator. Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be fatal if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 17.1 mm Hg @ 20 C FLASH POINT 96.8 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. Open carefully. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Vent periodically. Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 10-22-23-34 Risk Statements: Flammable. Harmful if swallowed. Toxic by inhalation. Causes burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOBUTYL METHYLXANTHINE (3:1-) CAS # 28822584 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Heart. Nerves. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at -20C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOBUTYLAMINE CAS # 78819 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . G . . J K . NFPA HAZARD CODES (H,F,R,O) 2 3 0 ACUTE TOXICTY RISK INDEX 3.3 - LD50 224.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 3.9 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 106.9 mm Hg @ 20 C FLASH POINT 15.8 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Store under nitrogen. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F-C Indication of Danger: Highly Flammable. Corrosive. R: 11-22-35 Risk Statements: Highly flammable. Harmful if swallowed. Causes severe burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 ppm DOE Short Term Exposure Limit 5 ppm DOE Ceiling Limit 6 ppm Immediately Dangerous to Life and Health 35 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOBUTYLENE OXIDE CAS # 558305 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 3 0 INHALATION HAZARD INHALATION RISK INDEX 3.2 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 221.4 mm Hg @ 20 C FLASH POINT 33 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Xi Indication of Danger: Highly Flammable. Irritant. R: 11 36/37/38 Risk Statements: Highly flammable. Irritating to eyes, respiratory system and skin. S: 16 26 36 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOBUTYLPHENYL PROPIONIC ACID CAS # 51146566 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 1 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 636.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOBUTYRALDEHYDE CAS # 78842 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 3 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3000.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 3.3 - LC50 23900.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 300.0 mm Hg @ 20 C FLASH POINT -2.2 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Oxidizing agents, Strong acids, Strong bases, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Use water spray to cool fire-exposed containers. Store at 2-8C Keep container closed. Keep away from heat, sparks, and open flame. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame\. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 1 Safety Statements: Keep away from sources of ignition - no smoking. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 25 ppm DOE Short Term Exposure Limit 300 ppm DOE Ceiling Limit 1500 ppm Immediately Dangerous to Life and Health 1500 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOBUTYRIC ACID CAS # 79312 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . G . . J K . NFPA HAZARD CODES (H,F,R,O) 1 2 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 280.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.4 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 1.5 mm Hg @ 20 C FLASH POINT 131 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Stench. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 21/22 Risk Statements: Harmful in contact with skin and if swallowed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .3 ppm DOE Short Term Exposure Limit 1 ppm DOE Ceiling Limit 6 ppm Immediately Dangerous to Life and Health 35 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOBUTYRIC ANHYDRIDE CAS # 97723 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 1 2 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1600.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.0 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 3.0 mm Hg @ 20 C FLASH POINT 154.4 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .1 ppm DOE Short Term Exposure Limit .3 ppm DOE Ceiling Limit 2 ppm Immediately Dangerous to Life and Health 10 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOBUTYRONITRILE CAS # 78820 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C D E . . . I J K . NFPA HAZARD CODES (H,F,R,O) 3 3 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4 - LD50 50.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 15514.5 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Readily absorbed through skin. Toxic if absorbed through skin. Eye Contact: May be fatal in contact with eyes. Inhalation: Toxic if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Eyes. Skin. Central nervous system. Cardiovascular system. SIGNS AND SYMPTOMS OF EXPOSURE May cause cyanosis (blue-gray coloring of skin and lips caused by lack of oxygen). This material can produce a cyanide like effect. Always have a cyanide first-aid kit present when using this material. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 46.4 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong acids, Strong bases, Strong oxidizing agents, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides Hydrogen cyanide Store at 2-8C open flame. Keep tightly closed. Keep away from heat, sparks, and REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F T Indication of Danger: Highly Flammable. Toxic. R: 11 23/24/25 36/37/38 Risk Statements: Highly flammable. Toxic by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 9 16 24/25 26 36/37/39 45 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 25 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 8 ppm DOE Short Term Exposure Limit 10 ppm DOE Ceiling Limit 18 ppm Immediately Dangerous to Life and Health 68 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOBUTYRYL CHLORIDE CAS # 79301 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 3 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. IRRITATION DATA Eyes Rabbit 0.1 ml 24H Remarks: Severe irritation effect PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 53.2 mm Hg @ 20 C FLASH POINT 46.4 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Alcohols, Oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 35 Risk Statements: Highly flammable. Causes severe burns. S: 16 23 26 36 45 Safety Statements: Keep away from sources of ignition - no smoking. Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOCITRIC ACID (DL-) CAS # 1637736 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOCITRIC ACID LACTONE CAS # 4702323 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAG Suitable: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOCITRIC DEHYDROGENASE CAS # 9028482 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOCYANATOMETHYLBUTYRIC ACID METHYL ESTER (2:3-) CAS # 30293868 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . L NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 172 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 23 26 36 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOCYTOSINE CAS # 108532 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . L NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1800.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36 Risk Statements: Harmful if swallowed. Irritating to eyes. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOFLURANE CAS # 26675467 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 4770.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Hydrogen fluoride REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2000 ppm DOE Short Term Exposure Limit 5000 ppm DOE Ceiling Limit 5000 ppm Immediately Dangerous to Life and Health 5000 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOINDOLINE CAS # 496128 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 202 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C Handle and store under inert gas. Keep tightly closed. Handle and store under nitrogen. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Handle and store under nitrogen. Store at 2-8%C SPECIAL REQUIREMENTS Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOLEUCINE (DL-) CAS # 443798 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOLEUCINE (FMOC,L-) CAS # 71989236 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOLEUCINE (L-) CAS # 73325 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The levorotary (l) forms of leucine, isoleucine, and valine have been found to have tumor-promoting activity for bladder carcinomas. Science 231, 843, 21 February 1986. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISONICOTINAMIDE CAS # 1453823 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLIN User Exposure: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISONICOTINIC ACID CAS # 55221 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong reducing agents. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Water spray. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISONICOTINIC ACID HYDRAZIDE CAS # 54853 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1250.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Nerves. Blood. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-38 Risk Statements: Harmful if swallowed. Irritating to skin. S: 37 Safety Statements: Wear suitable gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISONICOTINIC ACID OXIDE (N-) CAS # 13602125 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid chlorides, Acid anhydrides, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISONICOTINOYL CHLORIDE HYDROCHLORIDE CAS # 39178353 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Store at 2-8C Hygroscopic. Keep tightly closed. Store in a cool dry place. Store under nitrogen. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen. Store at 2-8%C SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISONIPECOTIC ACID CAS # 498942 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISONUTROSOACETIOPHENONE (2-) CAS # 532547 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPENTYL BENZOATE CAS # 94462 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .0450 mm Hg @ 20 C FLASH POINT 235 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPHORONE CAS # 78591 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . I J K . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 3 - LD50 1870.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX 1.1 - LC50 7000.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Vapor or mist is irritating to the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Central nervous system. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Exposure can cause: CNS depression. Narcotic effect. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .200 mm Hg @ 20 C FLASH POINT 204.8 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 21/22 36/37 40 Risk Statements: Harmful in contact with skin and if swallowed. Irritating to eyes and respiratory system. Limited evidence of a carcinogenic effect. S: 13 23 36/37/39 46 Safety Statements: Keep away from food, drink, and animal feedingstuffs. Do not breathe vapor. Wear suitable protective clothing, gloves, and eye/face protection. If swallowed, seek medical advice immediately and show this container or label. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 4 ppm ACGIH RECOMMENDED LIMITS ACGIH Ceiling Limit 5 ppm Immediately Dangerous to Life and Health 200 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 ppm DOE Short Term Exposure Limit 5 ppm DOE Ceiling Limit 5 ppm Immediately Dangerous to Life and Health 200 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPHTHALOYL DICHLORIDE CAS # 99638 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . L NFPA HAZARD CODES (H,F,R,O) 3 1 1 W INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 356 F Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Water, Alcohols, Oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Phosgene gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 21 34 37 Risk Statements: Harmful in contact with skin. Causes burns. Irritating to respiratory system. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPRENE CAS # 78795 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . C . . . . . I J K . NFPA HAZARD CODES (H,F,R,O) 1 4 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 1 - LD50 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 43090.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Exposure can cause: Inhalation of vapors may cause dizziness, an irregular heartbeat, narcosis, nausea, or asphyxiation. CNS depression. Narcotic effect. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 456.0 mm Hg @ 20 C FLASH POINT -65.2 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Ammonia, Alkali metals, Alcohols, Oxygen, Sulfuric acid, Ozone, Chlorosulfonic acid, Oleum. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8C Heat sensitive. Keep container closed. Keep away from heat, sparks, and open flame. REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. Store at 2-8%C SPECIAL REQUIREMENTS Heat sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F+ T Indication of Danger: Extremely Flammable. Toxic. R: 45 12 68 52/53 Risk Statements: May cause cancer. Extremely flammable. Possible risk of irreversible effects. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53 45 61 Safety Statements: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2 ppm DOE Short Term Exposure Limit 5 ppm DOE Ceiling Limit 1000 ppm Immediately Dangerous to Life and Health 4000 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPENYL ACETATE CAS # 108225 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 4 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure can cause: Nausea, dizziness, and headache. Narcotic effect. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 66 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC CORROSIVE INCOMPATIBILITIES:Oxidizing agents, Bases, Acids, Peroxides. FIRE EXTINGUISHER: For small (incipient) fires, use media such as"alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 9-16-29-33 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. Do not empty into drains. Take precautionary measures against static discharges. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPENYL CHLOROFORMATE CAS # 57933832 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Causes burns. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 50 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong bases, Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Store at 2-8C Keep tightly closed. Keep away from heat, sparks, and open flame. Handle and store under nitrogen. Vent periodically. Moisture sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. Open carefully. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Handle and store under nitrogen. Store at 2-8%C SPECIAL REQUIREMENTS Vent periodically. Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F-T Indication of Danger: Highly Flammable. Toxic. R: 11-23/24/25-34-36/37 Risk Statements: Highly flammable. Toxic by inhalation, in contact with skin and if swallowed. Causes burns. Irritating to eyes and respiratory system. S: 16-26-27-36/37/39-45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYL ACETATE CAS # 108214 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . . H . . . . NFPA HAZARD CODES (H,F,R,O) 1 3 0 ACUTE TOXICTY RISK INDEX 1.9 - LD50 6750.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.5 - LC50 50600.0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Vapor or mist is irritating to the eyes. Inhalation: Vapor or mist is irritating to the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure can cause: Nausea, headache, and vomiting. Narcotic effect. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 47.0 mm Hg @ 20 C FLASH POINT 39 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Acids, Bases, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F Xi Indication of Danger: Highly Flammable. Irritant. R: 11 36/37/38 Risk Statements: Highly flammable. Irritating to eyes, respiratory system and skin. S: 16 26 36 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 250 ppm OSHA Short Term Exposure Limit 310 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 100 ppm ACGIH Short Term Exposure Limit 200 ppm Immediately Dangerous to Life and Health 1800 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 250 ppm DOE Short Term Exposure Limit 310 ppm DOE Ceiling Limit 310 ppm Immediately Dangerous to Life and Health 1800 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYL ACETOACETATE CAS # 542085 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 159.8 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 38 Risk Statements: Irritating to skin. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYL BENZYL BROMIDE (4-) CAS # 73789863 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. - PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Store under inert gas. Moisture sensitive.- GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 23 26 36/37/39 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYL CHLORIDE CAS # 75296 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 2 4 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX 3.3 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Vapor or mist is irritating to the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Nerves. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 444.1 mm Hg @ 20 C FLASH POINT -5.8 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water may be effective for cooling, but may not effect extinguishment. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Store at 2-8C May develop pressure. Open carefully. Keep container closed. Keep away from heat, sparks, and open flame. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. Store at 2-8%C SPECIAL REQUIREMENTS May develop pressure. Open carefully. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F Xn Indication of Danger: Highly Flammable. Harmful. R: 11 20/21/22 Risk Statements: Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. S: 9 29 Safety Statements: Keep container in a well-ventilated place. Do not empty into drains. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 50 ppm DOE Short Term Exposure Limit 150 ppm DOE Ceiling Limit 15000 ppm Immediately Dangerous to Life and Health 15000 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYL ETHER CAS # 108203 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 1 4 2 ACUTE TOXICTY RISK INDEX 1.8 - LD50 8470.0 mg/Kg NEUROTOXIC - RISK INDEX 3.0 INHALATION HAZARD INHALATION RISK INDEX 2.7 - LC50 *** ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Narcotic effect. Nausea, headache, and vomiting. Exposure can cause: PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable Explosive VAPOR PRESSURE 120.0 mm Hg @ 20 C FLASH POINT -20.2 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area Forms explosive unstable peroxides Test periodically or discard SEGREGATION: SHELF # 3 STORAGE GROUP(S): k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Store under nitrogen. Unsuitable: Forms explosive peroxides on prolonged storage GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11-19-66-67 Risk Statements: Highly flammable. May form explosive peroxides. Repeated exposure may cause skin dryness or cracking. Vapors may cause drowsiness and dizziness. S: 9-16-29-33 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. Do not empty into drains. Take precautionary measures against static discharges. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 500 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 250 ppm ACGIH Short Term Exposure Limit 310 ppm Immediately Dangerous to Life and Health 1400 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 310 ppm DOE Short Term Exposure Limit 310 ppm DOE Ceiling Limit 310 ppm Immediately Dangerous to Life and Health 1400 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYL ISOCYANATE CAS # 1795488 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . G . . . . L NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SENSITIZATION Sensitization: May cause allergic reaction. SIGNS AND SYMPTOMS OF EXPOSURE Repeated exposure may cause asthma. Prolonged contact can cause: Nausea, dizziness, and headache. Lung irritation, chest pain, and edema which may be fatal. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 26.6 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Water, Alcohols, Strong bases, Amines, Acids, Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Store at 2-8C Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Handle Moisture sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Handle and store under nitrogen. Store at 2-8%C SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F T+ Indication of Danger: Highly Flammable. Very toxic. R: 11 26 36/37/38 42 Risk Statements: Highly flammable. Very toxic by inhalation. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation. S: 16 23 26 36/37/39 45 Safety Statements: Keep away from sources of ignition - no smoking. Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYL PIPERAZINE CAS # 4318427 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 2830.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 130 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 10 21 36/37/38 Risk Statements: Flammable. Harmful in contact with skin. Irritating to eyes, respiratory system and skin. S: 16 26 36 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYL PIPERIDONE (1,4-) CAS # 5355680 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYL THIOGALACTOPYRANOSIDE CAS # 367931 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 2 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged or repeated exposure to skin causes defatting and dermatitis. Symptoms include nausea, vomiting, anorexia, weakness, dizziness, vertigo, headache, and sweating. Damage to the kidneys. Damage to the liver. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Explosive Forms explosive unstable peroxides Test periodically or discard SEGREGATION: SHELF # 3 STORAGE GROUP(S): k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Store at 2-8C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 19-40-66 Risk Statements: May form explosive peroxides. Limited evidence of a carcinogenic effect. Repeated exposure may cause skin dryness or cracking. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYL THIOGLUCOPYRANOSIDE (BETA,D-) CAS # 19165118 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. Central nervous system. Damage to the kidneys. Damage to the liver. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea, dizziness, and headache. Damage to the kidneys. Damage to the liver. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Oxygen, Oxidizing agents, Halogens, Reducing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water may be effective for cooling, but may not effect extinguishment. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Store at -20C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store at -20%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 46 20/21/22 36/37/38 Risk Statements: May cause cancer. May cause heritable genetic damage. Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 53 26 36/37/39 45 Safety Statements: Avoid exposure - obtain special instructions before use. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLACRYLAMIDE (N-) CAS # 2210255 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . J K . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.1 - LD50 375.0 mg/Kg INHALATION RISK INDEX 1.9 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .480 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36 Risk Statements: Harmful if swallowed. Irritating to eyes. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLAMINE CAS # 75310 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D E . G H . J K . NFPA HAZARD CODES (H,F,R,O) 3 4 0 ACUTE TOXICTY RISK INDEX 3 - LD50 550.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 4.0 - LC50 9800.0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Toxic if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes burns. Inhalation: Harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 475.6 mm Hg @ 20 C FLASH POINT -.4 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F+-Xi Indication of Danger: Extremely Flammable. Irritant. R: 12-36/37/38 Risk Statements: Extremely flammable. Irritating to eyes, respiratory system and skin. S: 16-26-29 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Do not empty into drains. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 5 ppm OSHA Short Term Exposure Limit 10 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 5 ppm ACGIH Short Term Exposure Limit 10 ppm Immediately Dangerous to Life and Health 750 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 ppm DOE Short Term Exposure Limit 10 ppm DOE Ceiling Limit 150 ppm Immediately Dangerous to Life and Health 750 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLBENZALDEHYDE (4-) CAS # 122032 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1390.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .0724 mm Hg @ 20 C FLASH POINT 206.6 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLBENZOIC ACID (4-) CAS # 536663 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLCYCLOHEXYLAMINE (N-) CAS # 1195422 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Severe irritation or burns. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged contact can cause: To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 114.8 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC CORROSIVE INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Strong oxidizing agents Carbon dioxide. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water may be effective for cooling, but may not effect extinguishment. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 10 36/37/38 Risk Statements: Flammable. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLIDENEINOSINE (ORTHO,2',3'-) CAS # 2140116 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: REACTIVE PROPERTIES STORAGE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLIDINE BISPHENYLOXAZOLINE (2,2':4:2-) CAS # 131457460 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 230 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at -20C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLIDINE BISPHENYLOXAZOLINE (TERT,2,2':4:2-) CAS # 131833937 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLIMIDAZOLE (2-) CAS # 36947689 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLINDOLE (6-) CAS # 32996240 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K L NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 440.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause skin sensitization Sensitization: Strong sensitizer. skin: May cause skin sensitization SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 43 Risk Statements: Harmful if swallowed. May cause sensitization by skin contact. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLLITHIUM CAS # 1888751 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . I . . . NFPA HAZARD CODES (H,F,R,O) 3 4 1 W SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT -31 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Lithium oxides Store at 2-8C Keep tightly closed. Keep away from heat, sparks, and open flame. Handle and store under argon. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Handle and store under argon. Store at 2-8%C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F+ C Indication of Danger: Extremely Flammable. Corrosive. R: 12 20/22 34 14 Risk Statements: Extremely flammable. Harmful by inhalation and if swallowed. Causes burns. Reacts violently with water. S: 16 33 36/37/39 45 Safety Statements: Keep away from sources of ignition - no smoking. Take precautionary measures against static discharges. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLMAGNESIUM BROMIDE CAS # 920398 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . I . . . NFPA HAZARD CODES (H,F,R,O) 0 0 2 W SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Can cause CNS depression. Exposure can cause: Narcotic effect. Unconsciousness. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable Explosive Forms explosive unstable peroxides Test periodically or discard Reacts violently with water SEGREGATION: SHELF # 3 STORAGE GROUP(S): b - Pyrophoric/Water Reactive k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Acids, Water, Bases, Oxidizing agents, Oxygen. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen bromide gas Magnesium oxide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 14 19 20/21/22 34 Risk Statements: Highly flammable. Reacts violently with water. May form explosive peroxides. Harmful by inhalation, in contact with skin and if swallowed. Causes burns. S: 16 23 26 36/37/39 45 Safety Statements: Keep away from sources of ignition - no smoking. Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLMETHACRYLAMIDE (N-) CAS # 13749616 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . F G . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLMETHYLAMINE (N-) CAS # 4747211 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 214.6 mm Hg @ 20 C FLASH POINT -4 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 34 Risk Statements: Highly flammable. Causes burns. S: 16 26 36/37/39 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLPYRIDINE (4-) CAS # 696300 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 152 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLSULFONYL CHLORIDE CAS # 10147372 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 1 W INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes burns. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 12.4 mm Hg @ 20 C FLASH POINT 186.8 F Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Water, Strong bases, Oxidizing agents, Alcohols. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 28 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOPROPYLTOLUENE (4-) CAS # 99876 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 2 - LD50 4750.0 mg/Kg INHALATION RISK INDEX 1.5 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 1.5 mm Hg @ 20 C FLASH POINT 116.6 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 10 36/37/38 Risk Statements: Flammable. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 75 mg/m3 DOE Short Term Exposure Limit 250 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOQUINOLINE CAS # 119653 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . E . . . . J K . NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 615.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Toxic if absorbed through skin. Readily absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .0284 mm Hg @ 20 C FLASH POINT 215.6 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 22 24 38 Risk Statements: Harmful if swallowed. Toxic in contact with skin. Irritating to skin. S: 36/37 45 Safety Statements: Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOQUINOLINESULFONYLMETHYLPIPERAZINE (1:5,2-) CAS # 84477872 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE An inhibitor of protein kinase. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloride gas Store at -20C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOSORBIDE DIMETHYL ETHER CAS # 5306854 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 248 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 23 24/25 Safety Statements: Do not breathe vapor. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOVALERALDEHYDE CAS # 590863 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 3 0 ACUTE TOXICTY RISK INDEX 1.9 - LD50 5600.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.4 - LC50 42700.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea, headache, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 30.0 mm Hg @ 20 C FLASH POINT 23 F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Oxidizing agents, Strong bases, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Handle and store under inert gas. Air and light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Xi Indication of Danger: Highly Flammable. Irritant. R: 11 36 Risk Statements: Highly flammable. Irritating to eyes. S: 7 16 26 36 Safety Statements: Keep container tightly closed. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOVALERIC ACID CAS # 503742 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . D . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 2 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 1.3 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmfu if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .380 mm Hg @ 20 C FLASH POINT 165.2 F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Bases, Oxidizing agents, Reducing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOVANILLIN CAS # 621590 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1580.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .001300 mm Hg @ 20 C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOXAZOLE CAS # 288142 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 53.6 F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 16 Safety Statements: Keep away from sources of ignition - no smoking. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ISOXAZOLE CARBONYL CHLORIDE (5-) CAS # 62348134 HAZARDOUS CHEMICAL OF CONCERN A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . G . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 W INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes burns. Inhalation: Harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under inert gas\. SPECIAL REQUIREMENTS Reacts violently with water. Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 20/21/22 34 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ITACONIC ACID CAS # 97654 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Bases, Oxidizing agents, Reducing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. STORAGE: Keep container closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ITACONIC ANHYDRIDE CAS # 2170038 A Special Carcinogen E Dermal Hazard I Neurotoxin B Human Terato\Repro Haz F Corrosive J Suspect Carcinogen C Highly Toxic G Eye Damage K Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. 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R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. 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